Citation: Jing Li, Suyao Liu, Huaike Zhang, Enjing Lü, Pengju Ren, Jie Ren. Synthesis and characterization of an unusual snowflake-shaped ZSM-5 zeolite with high catalytic performance in the methanol to olefin reaction[J]. Chinese Journal of Catalysis, ;2016, 37(2): 308-315. doi: 10.1016/S1872-2067(15)60979-2 shu

Synthesis and characterization of an unusual snowflake-shaped ZSM-5 zeolite with high catalytic performance in the methanol to olefin reaction

Jing Li ^a,b ,
Suyao Liu ^a,b ,
Huaike Zhang ^a,c ,
Enjing Lü ^c ,
Pengju Ren ^a,c ,
Jie Ren ^a,c,,

1.
a State Engineering Laboratory for Indirect Coal Liquefaction, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, Shanxi, China;
2.
b University of Chinese Academy of Sciences, Beijing 100049, China;
3.
c National Energy Research Center for Clean Fuels, Synfuels China Co., Ltd., Beijing 101407, China

Corresponding author: Jie Ren,
Received Date: 23 July 2015
Available Online: 23 September 2015

The ZSM-5 zeolite with an unusual snowflake-shaped morphology was hydrothermally synthesized for the first time, and compared with common ellipsoidal and boat-like shaped samples. These samples were characterized by N₂ adsorption-desorption, X-ray fluorescence spectroscopy, scanning electron microscopy, X-ray diffraction, magic angle spinning nuclear magnetic resonance, temperature-programmed desorption of ammonia, and infrared spectroscopy of pyridine adsorption. The results suggest that the BET surface area and SiO₂/Al₂O₃ ratio of these samples are similar, while the snowflake-shaped ZSM-5 zeolite possesses more of the (101) face, and distortion, dislocation, and asymmetry in the framework, resulting in a larger number of acid sites than the conventional samples. Catalysts for the methanol to olefin (MTO) reaction were prepared by loading Ca on the samples. The snowflake-shaped Ca/ZSM-5 zeolite exhibited excellent selectivity for total light olefin (72%) and propene (39%) in MTO. The catalytic performance influenced by the morphology can be mainly attributed to the snowflake-shaped ZSM-5 zeolite possessing distortion, dislocation, and asymmetry in the framework, and lower diffusion limitation than the conventional samples.
- ZSM-5 zeolite,
- Modification,
- Methanol to olefins
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