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Citation: Xuehua Yu, Zhen Zhao, Yuechang Wei, Jian Liu, Jianmei Li, Aijun Duan, Guiyuan Jiang. Synthesis of K-doped three-dimensionally ordered macroporous Mn0.5Ce0.5Oδ catalysts and their catalytic performance for sootoxidation[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1957-1967. doi: 10.1016/S1872-2067(15)60949-4 shu

Synthesis of K-doped three-dimensionally ordered macroporous Mn0.5Ce0.5Oδ catalysts and their catalytic performance for sootoxidation

  • 1.

    a State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China;

  • Corresponding author: Zhen Zhao, 
  • Received Date: 21 June 2015
    Available Online: 2 July 2015

    Fund Project: 国家自然科学基金(21177160, 21303263, 21477164) (21177160, 21303263, 21477164) 北京市新星计划(Z141109001814072) (Z141109001814072) 高等学校博士学科点专项科研基金(20130007120011) (20130007120011) 中国石油大学(北京)科学基金(2462013YJRC13, 2462013BJRC003). (北京)科学基金(2462013YJRC13, 2462013BJRC003)

  • A series of K-doped Mn0.5Ce0.5Oδ (K-MCO) catalysts with three-dimensionally ordered macroporous (3DOM) structure and different K loadings were successfully synthesized using simple methods. These catalysts exhibited well-defined 3DOM nanostructure, which consisted of extensive interconnecting networks of spherical voids. The effects of the calcination temperature and calcination time on the morphological characteristics and crystalline forms of the catalysts were systematically studied. The catalysts showed high catalytic activity for the combustion of soot. 3DOM 20% K-MCO-4h catalyst, in particular, showed the highest catalytic activity of all of the catalysts studied (e.g., T50 = 331 ℃ and SmCO2 = 95.3%). The occurrence of structural and synergistic effects among the K, Mn, and Ce atoms in the catalysts was favorable for enhancing their catalytic activity towards the combustion of diesel soot. Furthermore, the temperatures required for the complete combustion of the soot (<400 ℃) were well within the exhaust temperature range (175-400 ℃), which means that the accumulated soot can be removed under the conditions of the diesel exhaust gas. These catalysts could therefore be used in numerous practical applications because they are easy to synthesize, exhibit high catalytic activity, and can be made from low cost materials.
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    1. [1]

      [1] Fino D, Specchia V. Powder Technol, 2008, 180: 64

    2. [2]

      [2] Twigg M V. Appl Catal B, 2007, 70: 2

    3. [3]

      [3] Heal M R, Kumar P, Harrison R M. Chem Soc Rev, 2012, 41: 6606

    4. [4]

      [4] Neeft J P A, Makkee M, Moulijn J A. Appl Catal B, 1996, 8: 57

    5. [5]

      [5] Bueno-López A. Appl Catal B, 2014, 146: 1

    6. [6]

      [6] Neeft J P A, van Pruissen O P, Makkee M, Moulijn J A. Appl Catal B, 1997, 12: 21

    7. [7]

      [7] Arandiyan H, Dai H X, Deng J G, Liu Y X, Bai B Y, Wang Y, Li X W, Xie S H, Li J H. J Catal, 2013, 307: 327

    8. [8]

      [8] Stein A, Wilson B E, Rudisill S G. Chem Soc Rev, 2013, 42: 2763

    9. [9]

      [9] Xu J F, Liu J, Zhao Z, Xu C M, Zheng J X, Duan A J, Jiang G Y. J Catal, 2011, 282: 1

    10. [10]

      [10] Zhang G Z, Zhao Z, Xu J F, Zheng J X, Liu J, Jiang G Y, Duan A J, He H. Appl Catal B, 2011, 107: 302

    11. [11]

      [11] Guilhaume N, Bassou B, Bergeret G, Bianchi D, Bosselet F, Desmartin-Chomel A, Jouguet B, Mirodatos C. Appl Catal B, 2012, 119-120: 287

    12. [12]

      [12] Van Craenenbroeck J, Andreeva D, Tabakova T, Van Werde K, Mullens J, Verpoort F. J Catal, 2002, 209: 515

    13. [13]

      [13] Zhong F L, Zhong Y J, Xiao Y H, Cai G H, Zheng Y, Wei K M. Chin J Catal (钟富兰, 钟喻娇, 肖益鸿, 蔡国辉, 郑勇, 魏可镁. 催化学报), 2011, 32: 1469

    14. [14]

      [14] Wei Y C, Liu J, Zhao Z, Chen Y S, Xu C M, Duan A J, Jiang G Y, He H. Angew Chem Int Ed, 2011, 50: 2326

    15. [15]

      [15] Wei Y C, Zhao Z, Liu J, Liu S T, Xu C M, Duan A J, Jiang G Y. J Catal, 2014, 317: 62

    16. [16]

      [16] Yu X H, Li J M, Wei Y C, Zhao Z, Liu J, Jin B F, Duan A J, Jiang G Y. Ind Eng Chem Res, 2014, 53: 9653

    17. [17]

      [17] Shi X Y, Yu Y B, Xue L, He H. Chin J Catal (石晓燕, 余运波, 薛莉, 贺泓. 催化学报), 2014, 35: 1504

    18. [18]

      [18] Li W N, Yuan J K, Shen X F, Gomez Mower S, Xu L P, Sithambaram S, Aindow M, Suib S L. Adv Funct Mater, 2006, 16: 1247

    19. [19]

      [19] Tikhomirov K, Krocher O, Elsener M, Wokaun A. Appl Catal B, 2006, 64: 72

    20. [20]

      [20] Sheng Y Q, Zhou Y, Lu H F, Zhang Z K, Chen Y F. Chin J Catal (盛叶琴, 周瑛, 卢晗锋, 张泽凯, 陈银飞. 催化学报), 2013, 34: 567

    21. [21]

      [21] Wu X D, Liu S, Weng D, Lin F, Ran R. J Hazard Mater, 2011, 187: 283

    22. [22]

      [22] Gálvez M E, Ascaso S, Stelmachowski P, Legutko P, Kotarba A, Moliner R, Lázaro M J. Appl Catal B, 2014, 152-153: 88

    23. [23]

      [23] Ogura M, Kimura R, Ushiyama H, Nikaido F, Yamashita K, Okubo T. ChemCatChem, 2014, 6: 479

    24. [24]

      [24] Kimura R, Wakabayashi J, Elangovan S P, Ogura M, Okubo T. J Am Chem Soc, 2008, 130: 12844

    25. [25]

      [25] Zhang Z L, Zhang Y X, Wang Z P, Gao X Y. J Catal, 2010, 271: 12

    26. [26]

      [26] Guo X, Meng M, Dai F F, Li Q, Zhang Z L, Jiang Z, Zhang S, Huang Y Y. Appl Catal B, 2013, 142-143: 278

    27. [27]

      [27] Legutko P, Jakubek T, Kaspera W, Stelmachowski P, Sojka Z, Kotarba A. Catal Commun, 2014, 43: 34

    28. [28]

      [28] Shan W J, Yang L H, Ma N, Yang J L. Chin J Catal (单文娟, 杨利花, 马娜, 杨佳丽. 催化学报), 2012, 33: 970

    29. [29]

      [29] Li Q, Wang X, Xin Y, Zhang Z L, Zhang Y X, Hao C, Meng M, Zheng L R, Zheng L. Sci Rep, 2014, 4: 4725

    30. [30]

      [30] Carrascull A L, Ponzi M I, Ponzi E N. Ind Eng Chem Res, 2003, 42: 692

    31. [31]

      [31] Gómez L E, Boix A V, Miró E E. Catal Today, 2013, 216: 246

    32. [32]

      [32] Delimaris D, Ioannides T. Appl Catal B, 2008, 84: 303

    33. [33]

      [33] Wang H, Liu J, Zhao Z, Wei Y C, Xu C M. Catal Today, 2012, 184: 288

    34. [34]

      [34] Yadav G D, Mewada R K. Chem Eng J, 2013, 221: 500

    35. [35]

      [35] Ma L, Wang D S, Li J H, Bai B Y, Fu L X, Li Y D. Appl Catal B, 2014, 148-149: 36

    36. [36]

      [36] Wang R H, Li J H. Environ Sci Technol, 2010, 44: 4282

    37. [37]

      [37] King'ondu C K, Opembe N, Chen C H, Ngala K, Huang H, Iyer A, Garcés H F, Suib S L. Adv Funct Mater, 2011, 21: 312

    38. [38]

      [38] Ura B, Trawczyński J, Kotarba A, Bieniasz W. Illán-Gómez M J, Bueno-López A, López-Suárez F E. Appl Catal B, 2011, 101: 169

    39. [39]

      [39] Legutko P, Jakubek T, Kaspera W, Stelmachowski P, Sojka Z, Kotarba A. Catal Commun, 2014, 43: 34

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