Citation: Oleksiy V. Khavryuchenko, Volodymyr D. Khavryuchenko, Dangsheng Su. Spin catalysts: A quantum trigger for chemical reactions[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1656-1661. doi: 10.1016/S1872-2067(15)60948-2 shu

Spin catalysts: A quantum trigger for chemical reactions

1.
a Computation Chemistry Group, Revutskogo Str. 13, App. 149, Kyiv UA-02091, Ukraine;

Corresponding author: Oleksiy V. Khavryuchenko, Dangsheng Su,
Received Date: 15 April 2015
Available Online: 28 June 2015

Spin catalysis allows restrictions of the spin conservation rule to be overcome, and, moreover, provides a tool for fine control of elementary reactions. Spin-conductive solid catalysts make processes over surfaces strongly correlated and also can trigger the direction of the reaction via external magnetic field application. Activation/deactivation of O₂ and non-polar small molecules, homolytic bond cleavage, and coupling of radicals are within the practical scope of spin catalysis.
- Catalysis,
- Spin chemistry,
- Homolytic bond cleavage,
- Oxidative processes,
- Radicals coupling
1. [1]
  [1] Minaev B F, Ågren H. Int J Quantum Chem, 1998, 57: 519
2. [2]
  [2] Buchachenko A L, Berdinsky V L. Chem Rev, 2002, 102: 603
3. [3]
  [3] Buchachenko A L, Berdinsky V L. Russ Chem Rev, 2004, 73: 1033
4. [4]
  [4] Schwarz H. Int J Mass Spectr, 2004, 237: 75
5. [5]
  [5] Schröder D, Schwarz H. Reactivity Concepts for Oxidation Catalysis: Spin and Stoichiometry Problems in Dioxygen Activation. In: Quinkert G, Kisakürek M V Eds. Essays in Contemporary Chemistry: From Molecular Structure towards Biology. New York: Wiley-VCH, 2007. 131
6. [6]
  [6] Salikhov K M, Molin Yu N, Sagdeev R Z, Buchachenko A L. Spin Polarization and Magnetic Effects in Radical Reactions. Budapest: Akademiai Kiado, 1984. 419
7. [7]
  [7] Turro N J, Arora K S. Macromolecules, 1986, 19: 42
8. [8]
  [8] Wang J F, Welsh K M, Waterman K C, Fehiner P, Doubleday C Jr, Turro N J. J Phys Chem, 1988, 92: 3730
9. [9]
  [9] Sakaguchi Y, Hayashi H. Chem Phys, 1992, 162: 119
10. [10]
  [10] Yamaguchi K, Shoji M, Isobe H, Kitagawa Y, Yamada S, Kawakami T, Yamanaka S, Okumura M. Polyhedron, 2013, 66: 228
11. [11]
  [11] Prabhakar R, Siegbahn P E M, Minaev B F, Ågren H. J Phys Chem B, 2004, 108: 13882
12. [12]
  [12] Himo F, Siegbahn P E M. Chem Rev, 2003, 103: 2421
13. [13]
  [13] Minaev B F, Murugan N A, Ågren H. Int J Quantum Chem, 2013, 113: 1847
14. [14]
  [14] Yamanaka S, Saito T, Kanda K, Isobe H, Umena Y, Kawakami K, Shen J R, Kamiya N, Okumura M, Nakamura H, Yamaguchi K. Int J Quantum Chem, 2012, 112: 321
15. [15]
  [15] Stass D V, Woodward J R, Timmel C R, Hore P J, McLauchlan K A. Chem Phys Lett, 2000, 329: 15
16. [16]
  [16] Turro N J. J Org Chem, 2011, 76: 9863
17. [17]
  [17] Terenzi C, Bouguet-Bonnet S, Canet D. J Phys Chem Lett, 2015, 6: 1611
18. [18]
  [18] Mori Y, Sakaguchi Y, Hayashi H. J Phys Chem A, 2002, 106: 4453
19. [19]
  [19] Mi Q, Chernick E T, McCamant D W, Weiss E A, Ratner M A, Wasielewski M R. J Phys Chem A, 2006, 110: 7323
20. [20]
  [20] Cohen A E. J Phys Chem A, 2009, 113: 11084
21. [21]
  [21] Isobe H, Yamanaka S, Kuramitsu S, Yamaguchi K. J Am Chem Soc, 2008, 130: 132
22. [22]
  [22] Maeyama T, Matsui H, Yago T, Wakasa M. J Phys Chem C, 2010, 114: 22190
23. [23]
  [23] Okazaki M, Toriyama K, Oda K, Kasai T. Phys Chem Chem Phys, 2002, 4: 1201
24. [24]
  [24] Okazaki M, Tanimoto Y, Konishi Y, Toriyama K. J Phys Chem, 1996, 100: 9403
25. [25]
  [25] Khavryuchenko O V, Frank B, Trunschke A, Hermann K, Schlögl R. J Phys Chem C, 2013, 117: 6225
26. [26]
  [26] Rodgers C T. Pure Appl Chem, 2009, 81: 19
27. [27]
  [27] Schweitzer C, Schmidt R. Chem Rev, 2003, 103: 1685
28. [28]
  [28] Baik M H, Newcomb M, Friesner R A, Lippard S J. Chem Rev, 2003, 103: 2385
29. [29]
  [29] Cloonan M O. Int J Hydrogen Energy, 2007, 32: 159
30. [30]
  [30] Markofsky S B. Nitro Compounds, Aliphatic. Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH, 2000. 291
31. [31]
  [31] Minaev B F. J Mol Catal A, 2001, 171: 53
32. [32]
  [32] Pietrzyk P, Zasada F, Piskorz W, Kotarba A, Sojka Z. Catal Today, 2007, 119: 219
33. [33]
  [33] Kruczała K, Szczubiałka K, Łańcucki Ł, Zastawny I, Góra-Marek K, Dyrek K, Sojka Z. Spectrochim Acta A, 2008, 69: 1337
34. [34]
  [34] Spier E, Neuenschwander U, Hermans I. Angew Chem Int Edt, 2013, 52: 1581
35. [35]
  [35] Busch M, Ahlberg E, Panas I. Phys Chem Chem Phys, 2011, 13: 15062
36. [36]
  [36] Khavryuchenko O V, Stus N V, Peslherbe G H. Solid State Commun, 2012, 152: 2138
37. [37]
  [37] Khavryuchenko O V, Khavryuchenko V D, Lisnyak V V, Peslherbe G H. Chem Phys Lett, 2011, 513: 261
38. [38]
  [38] Schlögl R. Adv Catal, 2013, 56: 103
39. [39]
  [39] Arrigo R, Schuster M E, Xie Z, Yi Y, Wowsnick G, Sun L L, Hermann K E, Friedrich M, Kast P, Hävecker M, Knop-Gericke A, Schlögl R. ACS Catal, 2015, 5: 2740
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