Citation: Yanwei Ren, Jiaxian Lu, Ou Jiang, Xiaofei Cheng, Jun Chen. Amine-grafted on lanthanide metal-organic frameworks: Three solid base catalysts for Knoevenagel condensation reaction[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1949-1956. doi: 10.1016/S1872-2067(15)60945-7 shu

Amine-grafted on lanthanide metal-organic frameworks: Three solid base catalysts for Knoevenagel condensation reaction

Yanwei Ren ^a,, ,
Jiaxian Lu ^a ,
Ou Jiang ^b ,
Xiaofei Cheng ^a ,
Jun Chen ^b

1.
a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, Guangdong, China;

Corresponding author: Yanwei Ren,
Received Date: 29 May 2015
Available Online: 3 July 2015
Fund Project: 国家自然科学基金(21372087). (21372087)

A post-synthetic modification strategy has been used to prepare three solid base catalysts, including Er(btc)(ED)_0.75(H₂O)_0.25 (2, btc = 1,3,5-benzenetricarboxylates, ED = 1,2-ethanediamine), Er(btc)(PP)_0.55(H₂O)_0.45 (3, PP = piperazine), and Er(btc)(DABCO)_0.15(H₂O)_0.85 (4, DABCO = 1,4- diazabicyclo[2.2.2]octane), by grafting three different diamines onto the coordinatively unsaturated Er(III) ions into the channels of the desolvated lanthanide metal-organic framework (Er(btc)). The resulting metal-organic frameworks were characterized by elemental analysis, thermogravimetric analysis, powder X-ray diffraction, and N₂ adsorption. Based on its higher loading ratio of the diamine, as well as its greater stability and porosity, catalyst 2 exhibited higher catalytic activity and reusability than catalysts 3 and 4 for the Knoevenagel condensation reaction. The catalytic mechanism of 2 has also been investigated using size-selective catalysis tests.
- Lanthanide metal-organic framework,
- Post-synthetic modification,
- Solid base catalyst,
- Knoevenagel condensation reaction,
- Size-selective catalysis
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