Citation: Junrui Li, Xiaohong Li, Yue Ding, Peng Wu. Pt nanoparticles entrapped in ordered mesoporous carbons: An efficient catalyst for the liquid-phase hydrogenation of nitrobenzene and its derivatives[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1995-2003. doi: 10.1016/S1872-2067(15)60937-8 shu

Pt nanoparticles entrapped in ordered mesoporous carbons: An efficient catalyst for the liquid-phase hydrogenation of nitrobenzene and its derivatives

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China

Corresponding author: Xiaohong Li,
Received Date: 21 May 2015
Available Online: 17 June 2015
Fund Project: 国家自然科学基金(21273076, 21373089) (21273076, 21373089) 浙江师范大学浙江省省属高校“化学”重中之重学科“先进催化材料”教育部重点实验室开放课题(ZJHX2013) (ZJHX2013) 上海市重点学科建设项目(B409). (B409)

Pt nanoparticles entrapped in ordered mesoporous CMK-3 carbons with p6mm symmetry were prepared using a facile impregnation method, and the resulting materials were characterized using X-ray diffraction spectroscopy, N₂ adsorption-desorption, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The Pt nanoparticles were highly dispersed in the CMK-3 with 43.7% dispersion. The Pt/CMK-3 catalyst was an effective catalyst for the liquid-phase hydrogenation of nitrobenzene and its derivatives under the experimental conditions studied here. The Pt/CMK-3 catalyst was more active than commercial Pt/C catalyst in most cases. A highest turnover frequency of 43.8 s^-1was measured when the Pt/CMK-3 catalyst was applied for the hydrogenation of 2-methyl-nitrobenzene in ethanol under optimal conditions. It is worthy of note that the Pt/CMK-3 catalyst could be recycled easily, and could be reused at least fourteen times without any loss in activity or selectivity for the hydrogenation of nitrobenzene in ethanol.
- Pt nanoparticle,
- Nitrobenzene compound,
- Liquid-phase hydrogenation,
- Ordered mesoporous carbon
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Pt nanoparticles entrapped in ordered mesoporous carbons: An efficient catalyst for the liquid-phase hydrogenation of nitrobenzene and its derivatives

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com