Citation: Junrui Li, Xiaohong Li, Yue Ding, Peng Wu. Pt nanoparticles entrapped in ordered mesoporous carbons: An efficient catalyst for the liquid-phase hydrogenation of nitrobenzene and its derivatives[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1995-2003. doi: 10.1016/S1872-2067(15)60937-8 shu

Pt nanoparticles entrapped in ordered mesoporous carbons: An efficient catalyst for the liquid-phase hydrogenation of nitrobenzene and its derivatives

  • Corresponding author: Xiaohong Li, 
  • Received Date: 21 May 2015
    Available Online: 17 June 2015

    Fund Project: 国家自然科学基金(21273076, 21373089) (21273076, 21373089) 浙江师范大学浙江省省属高校“化学”重中之重学科“先进催化材料”教育部重点实验室开放课题(ZJHX2013) (ZJHX2013) 上海市重点学科建设项目(B409). (B409)

  • Pt nanoparticles entrapped in ordered mesoporous CMK-3 carbons with p6mm symmetry were prepared using a facile impregnation method, and the resulting materials were characterized using X-ray diffraction spectroscopy, N2 adsorption-desorption, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The Pt nanoparticles were highly dispersed in the CMK-3 with 43.7% dispersion. The Pt/CMK-3 catalyst was an effective catalyst for the liquid-phase hydrogenation of nitrobenzene and its derivatives under the experimental conditions studied here. The Pt/CMK-3 catalyst was more active than commercial Pt/C catalyst in most cases. A highest turnover frequency of 43.8 s-1 was measured when the Pt/CMK-3 catalyst was applied for the hydrogenation of 2-methyl-nitrobenzene in ethanol under optimal conditions. It is worthy of note that the Pt/CMK-3 catalyst could be recycled easily, and could be reused at least fourteen times without any loss in activity or selectivity for the hydrogenation of nitrobenzene in ethanol.
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