Citation:
Honggen Peng, Yue Peng, Xianglan Xu, Xiuzhong Fang, Yue Liu, Jianxin Cai, Xiang Wang. SnO2 nano-sheet as an efficient catalyst for CO oxidation[J]. Chinese Journal of Catalysis,
;2015, 36(11): 2004-2010.
doi:
10.1016/S1872-2067(15)60926-3
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Polycrystalline SnO2 fine powder consisting of nano-particles (SnO2-NP), SnO2 nano-sheets (SnO2-NS), and SnO2 containing both nano-rods and nano-particles (SnO2-NR+NP) were prepared and used for CO oxidation. SnO2-NS possesses a mesoporous structure and has a higher surface area, larger pore volume, and more active species than SnO2-NP, and shows improved activity. In contrast, although SnO2-NR+NP has only a slightly higher surface area and pore volume, and slightly more active surface oxygen species than SnO2-NP, it has more exposed active (110) facets, which is the reason for its improved oxidation activity. Water vapor has only a reversible and weak influence on SnO2-NS, therefore it is a potential catalyst for emission control processes.
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Keywords:
- SnO2 catalyst,
- Nano-sheet,
- Nano-rod,
- Exposed active facet,
- CO oxidation
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[1]
[1] Sasikala R, Gupta N M, Kulshreshtha S K. Catal Lett, 2001, 71: 69
-
[2]
[2] Batzill M, Diebold U. Progr Surf Sci, 2005, 79: 47
-
[3]
[3] Wang X, Xie Y C. Appl Catal B, 2001, 35: 85
-
[4]
[4] Yang G, Zhao H B, Zhao B Y. J Mater Sci, 2000, 35: 917
-
[5]
[5] Shao S F, Qiu X M, He D F, Koehn R, Guan N J, Lu X H, Bao N Z, Grimes C A. Nanoscale, 2011, 3: 4283
-
[6]
[6] Palacios-Padros A, Altomare M, Tighineanu A, Kirchgeorg R, Shrestha N K, Diez-Perez I, Caballero-Briones F, Sanz F, Schmuki P. J Mater Chem A, 2014, 2: 915
-
[7]
[7] Wang H K, Rogach A L. Chem Mater, 2014, 26: 123
-
[8]
[8] Han X, Xu X L, Liu W M, Wang X, Zhang R B. Solid State Sci, 2013, 20: 103
-
[9]
[9] Xu X L, Zhang R B, Zeng X R, Han X, Li Y C, Liu Y, Wang X. ChemCatChem, 2013, 5: 2025
-
[10]
[10] Wang X, Xiao L H, Peng H G, Liu W M, Xu X L. J Mater Chem A, 2014, 2: 5616
-
[11]
[11] Yu J, Zhao D, Xu X L, Wang X, Zhang N. ChemCatChem, 2012, 4: 1122
-
[12]
[12] Wang X, Tian J S, Zheng Y H, Xu X L, Liu W M, Fang X Z. ChemCatChem, 2014, 6: 1604
-
[13]
[13] Lan F, Wang X, Xu X L, Zhang R B, Zhang N. React Kinet Mech Catal, 2012, 106: 113
-
[14]
[14] Ma Y H, Wang X, You X J, Liu J J, Tian J S, Xu X L, Peng H G, Liu W M, Li C Q, Zhou W F, Yuan P, Chen X H. ChemCatChem, 2014, 6: 3366
-
[15]
[15] Tian J S, Peng H G, Xu X L, Liu W M, Ma Y H, Wang X, Yang X J. Catal Sci Technol, 2015, 5: 2270
-
[16]
[16] Li Y R, Peng H G, Xu X L, Peng Y, Wang X. RSC Adv, 2015, 5: 25755
-
[17]
[17] Wang X, Xie Y C. Z Phys Chem, 2002, 216: 919
-
[18]
[18] Wang X, Xie Y C. Catal Lett, 2001, 75: 73
-
[19]
[19] Croft G, Fuller M J. Nature, 1977, 269: 585
-
[20]
[20] Takeguchi T, Takeoh O, Aoyama S, Ueda J, Kikuchi R, Eguchi K. Appl Catal A, 2003, 252: 205
-
[21]
[21] Lu Z S, Ma D W, Yang L, Wang X B, Xu G L, Yang Z X. Phys Chem Chem Phys, 2014, 16: 12488
-
[22]
[22] Guo J, Zhang J, Ju D X, Xu H Y, Cao B Q. Powder Technol, 2013, 250: 40
-
[23]
[23] Zhang L X, Yin Y Y. Sens Actuator B, 2013, 185: 594
-
[24]
[24] Vuong D D, Trung K Q, Hung N H, Hieu N V, Chien N D. J Alloy Compd, 2014, 599: 195
-
[25]
[25] Kung M C, Kung H H. Top Catal, 2000, 10: 21
-
[26]
[26] Ramgir N S, Mulla I S, Vijayamohanan K P. J Phys Chem B, 2005, 109: 12297
-
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