Citation: Bingsen Zhang, Aiguo Zheng, Xiaoli Pan, Yiming Niu, Xiaoxin Zhang, Dangsheng Su, Baoning Zong. Microstructure of rapidly quenched Ni-Al based catalysts by advanced electron microscopy[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1662-1667. doi: 10.1016/S1872-2067(15)60925-1 shu

Microstructure of rapidly quenched Ni-Al based catalysts by advanced electron microscopy

1.
a Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, Liaoning, China;

Corresponding author: Dangsheng Su, Baoning Zong,
Received Date: 3 April 2015
Available Online: 3 June 2015
Fund Project: 石油化工催化材料与反应工程国家重点实验室(中国石油化工股份有限公司石油化工科学研究院)开放基金 (中国石油化工股份有限公司石油化工科学研究院)

The microstructure of air-sensitive Raney-type catalysts directly determines their activity and selectivity for a catalytic reaction. The fine structure of a rapidly quenched Ni-Al alloy doped with Fe and Cr (RQ Ni-Al-FC) was investigated by electron microscopy imaging and spectroscopic techniques, and its structure was successfully characterized by using a vacuum transfer holder in the transmission electron microscope. The microstructural comparison of pristine and passivated/combusted samples was discussed in detail. This work provides the structure of RQ Ni-Al based catalysts as a contribution to exploring their synthesis-structure-performance relationship.
- Nickel-aluminum based catalyst,
- Electron microscopy,
- Spectroscopy,
- Vacuum transfer holder,
- Microstructure
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沈阳化工大学材料科学与工程学院沈阳 110142