Citation: Hongcheng Gao, Yan Yan, Xiaohong Xu, Jiehui Yu, Huiling Niu, Wenxiu Gao, Wenxiang Zhang, Mingjun Jia. Catalytic epoxidation of olefin over supramolecular compounds of molybdenum oxide clusters and a copper complex[J]. Chinese Journal of Catalysis, ;2015, 36(11): 1811-1817. doi: 10.1016/S1872-2067(15)60919-6 shu

Catalytic epoxidation of olefin over supramolecular compounds of molybdenum oxide clusters and a copper complex

1.
a Department of Chemical Engineering, Chengde Petroleum College, Chengde 067000, Hebei, China;

Corresponding author: Mingjun Jia,
Received Date: 1 May 2015
Available Online: 29 May 2015
Fund Project: 国家自然科学基金(21173100和21320102001). (21173100和21320102001)

The catalytic epoxidation of olefin was investigated on two copper complex-modified molybdenum oxides with a 3D supramolecular structure, [Cu(bipy)]₄[Mo₁₅O₄₇]·2H₂O (1) and [Cu^I(bix)][(Cu^Ibix) (δ-Mo^VI₈O₂₆)_0.5] (2) (bipy = 4,4'-bipyridine, bix = 1,4-bis(imidazole-1-ylmethyl)benzene). Both compounds were catalytically active and stable for the epoxidation of cyclooctene, 1-octene, and styrene with tert-butyl hydroperoxide (t-BuOOH) as oxidant. The excellent catalytic performance was attributed to the presence of stable coordination bonds between the molybdenum oxide and copper complex, which resulted in the formation of easily accessible Mo species with high electropositivity. In addition, the copper complex also acted as an active site for the activation of t-BuOOH, thus improving these copper complex-modified polyoxometalates.
- Supramolecular compound,
- Molybdenum oxide cluster,
- Copper complex,
- Olefin,
- Epoxidation
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