Citation: Liping Zheng, Shuixin Xia, Xiuyang Lu, Zhaoyin Hou. Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1759-1765. doi: 10.1016/S1872-2067(15)60915-9 shu

Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite

1.
a Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou 310028, Zhejiang, China;

Corresponding author: Zhaoyin Hou,
Received Date: 23 March 2015
Available Online: 16 May 2015
Fund Project: 国家自然科学基金(21473155, 21273198, 21073159) (21473155, 21273198, 21073159) 浙江省自然科学基金(LZ12B03001). (LZ12B03001)

A series of Ca-Al hydrocalumite with different Ca/Al ratios (1-6) were synthesized and used in the transesterification of glycerol with dimethyl carbonate (DMC) to glycerol carbonate (GC) under mild conditions. The calcined Ca-Al hydrocalumites were active with a selectivity toward GC that reached 97% at 93% conversion of glycerol over the sample with Ca/Al = 2 at 70 ℃, 3 h, and DMC/glycerol = 3. The glycerol conversion depended mainly on the proportion of strong basic sites in the calcined Ca-Al catalysts. The Ca₁₂Al₁₄O₃₃ phase in the calcined catalysts was stable, but CaO was lost in recycle experiments and thus brought deactivation.
- Glycerol,
- Dimethyl carbonate,
- Transesterification,
- Glycerol carbonate,
- Calcium-aluminum hydrocalumite
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