Advanced Search

Citation: Maryam Moosavifar, Alieh Navid Arbat, Zolfaghar Rezvani, Kamellia Nejati. Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Cox/Mny) as nanocomposite catalysts for the epoxidation of cyclohexene[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1719-1725. doi: 10.1016/S1872-2067(15)60908-1 shu

Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Cox/Mny) as nanocomposite catalysts for the epoxidation of cyclohexene

  • 1.

    a Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh, Iran;

  • Corresponding author: Maryam Moosavifar, 
  • Received Date: 4 April 2015
    Available Online: 19 May 2015

  • Trinuclear metal clusters of Co, Mn and mixtures of Co/Mn including [Mn3(O)(CH3COO)6-(py)3]-Y, [Co3(O)(CH3COO)6-(py)3], [Co2Mn(O)(CH3COO)6-(py)3]-Y and [CoMn2(O)(CH3COO)6-(py)3]-Y] were prepared inside the nanocage of dealuminated Y zeolite by the template synthesis method. These catalysts were characterized by Fourier transform infrared, Ultraviolet-visible, field scanning electron microscopy, X-ray diffraction and atomic absorption spectroscopy. The encapsulated metal clusters showed good catalytic activity in the epoxidation of cyclohexene with H2O2/O2. Epoxide yields were 82.5% to 90.7%. NaBr was used as a promoter for the oxidation. The homonuclear metal clusters showed higher catalytic activity than the others and the highest efficiency was with the Mn3(O)-DAZY compound. The catalytic activity order was Mn3(O)-DAZY > Co3(O)-DAZY > Mn2Co(O)-DAZY > MnCo2(O)-DAZY.
  • 加载中
    1. [1]

      [1] Arunkumar C H. [PhD Dissertation]. Catalysis Division National Chemical Laboratory, Pune, India, 2002

    2. [2]

      [2] Que L Jr. Metal Clusters in Proteins. ACS Symposium Series, 1988, 372: 1

    3. [3]

      [3] Gunsalus I C, Sligar S G. Adv Enzymol Relat Areas Mol Biol, 1978, 47: 1

    4. [4]

      [4] Herron N. J Coord Chem, 1988, 19: 25

    5. [5]

      [5] Knops-Gerrits P P, de Vos D E, Jacobs P A. J Mol Catal A, 1997, 117: 57

    6. [6]

      [6] Maurya M R, Titinchi S J J, Chand S. J Mol Catal A, 2004, 214: 257

    7. [7]

      [7] Kantam M L, Ranganath K V S, Sateesh M, Kumar K B S, Choudary M B. J Mol Catal A, 2005, 225: 15

    8. [8]

      [8] Hardacre C, Katdare S P, Milroy D, Nancarrow P, Rooney D W, Thompson J M. J Catal, 2004, 227: 44

    9. [9]

      [9] Choudhary V R, Jana S K, Patil N S, Bhargava S K. Microporous Mesoporous Mater, 2003, 57: 21

    10. [10]

      [10] Salavati-Niasari M. J Mol Catal A, 2006, 245: 192

    11. [11]

      [11] Salavati-Niasari M. Chem Lett, 2005, 34: 1444

    12. [12]

      [12] Salavati-Niasari M. J Mol Catal A, 2008, 284: 97

    13. [13]

      [13] Bedioui F. Coord Chem Rev, 1994, 144: 39

    14. [14]

      [14] Barloy L, Lallier J P, Battioni P, Mansuy D, Pitfard Y, Tournoux M, Valim J B, Jones W. New J Chem, 1992, 16: 71

    15. [15]

      [15] Połtowicz J, Pamin K, Tabor E, Haber J, Adamski A, Sojka Z. Appl Catal A, 2006, 299: 235

    16. [16]

      [16] Xavier K O, Chacko J, Mohammed Yusuff K K. Appl Catal A, 2004, 258: 251

    17. [17]

      [17] Salama T M, Ahmed A H, El-Bahy Z M. Microporous Mesoporous Mater, 2006, 89: 251

    18. [18]

      [18] Jacob C R, Varkey S P, Ratnasamy P. Microporous Mesoporous Mater, 1998, 22: 465

    19. [19]

      [19] Zanjanchi M A, Tabatabaeian K, Moosavifar M. J Incl Phenom Macrocyc Chem, 2001, 40: 193

    20. [20]

      [20] Zakharov A N, Romanovsk B V. J Incl Phenom, 1985, 3: 389

    21. [21]

      [21] Moghadam M, Tangestaninejad S, Mirkhani V, Mohammadpoor- Baltork, Moosavifar M. J Mol Catal A, 2009, 302: 68

    22. [22]

      [22] Moosavifar M, Tangestaninejad S, Moghadam M, Mirkhani V, Mohammadpoor-Baltork I. J Mol Catal A, 2013, 377: 92

    23. [23]

      [23] Haber J, Pamin K, Poltowicz J. J Mol Catal A, 2004, 224: 153

    24. [24]

      [24] Rosa I L V, Manso C M C P, Serra O A, Iamamoto Y. J Mol Catal A, 2000, 160: 199

    25. [25]

      [25] Iamamoto Y, Ciuffi K J, Sacco H C, Prado C M C, de Moraes M, Nascimento OR. J Mol Catal A, 1994, 88: 167

    26. [26]

      [26] Vinhado F S, Prado-Manso C M C, Sacco H C, Iamamoto Y. J Mol Catal A, 2001, 174: 279

    27. [27]

      [27] Wang J, Lin Z, Han S Y, Eum M, Lee C W. J Ind Eng Chem, 2003, 9: 281

    28. [28]

      [28] Wang J, Jiang D, Baeg J O, Lee C W. J Ind Eng Chem, 2004, 10: 454

    29. [29]

      [29] Moghadam M, Tangestaninejad S, Mirkhani V, Mohammadpoor- Baltork I, Moosavifar M. Appl Catal A, 2009, 358: 157

    30. [30]

      [30] Moosavifar M, Alemi A, Marefat M R, Nouruzi N, Mahmoodi H. J Iran Chem Soc, 2014, 11: 1561

    31. [31]

      [31] Sulikowski B. J Phys Chem, 1993, 97: 1420

    32. [32]

      [32] Xavier K O, Chacko J, Yussuff K K M. Appl Catal A, 2004, 258: 251

    33. [33]

      [33] Serwicka E M, Połtowicz J, Bahranowski K, Olejniczak Z, Jones W. Appl Catal A, 2004, 275: 9

    34. [34]

      [34] Pires E L, Magalhães J C, Schuchardt U. Appl Catal A, 2000, 203: 231

    35. [35]

      [35] Øye G, Sjoblom J, Stocker M. Adv Colloid Interf Sci, 2001, 89-90: 439

    36. [36]

      [36] Maurya M R, Chandrak A K, Chand S. J Mol Catal A, 2007, 263: 227

    37. [37]

      [37] Partenheimer W. Catal Today, 1995, 23: 69

    38. [38]

      [38] Li G, Chen L, Bao J, Li T, Mei F. Appl Catal A, 2008, 346: 134

    39. [39]

      [39] Chen P, Fan B, Song M, Jin C, Ma J, Li R. Catal Commun, 2006, 7: 969

    40. [40]

      [40] Varkey S P, Ratnasamy C, Ratnasamy P. J Mol Catal A, 1998, 135: 295

    41. [41]

      [41] Davarpanah J, Kiasat A R. Catal Comm, 2014, 46: 75

    42. [42]

      [42] Farzaneh F, Sadeghi Y. J Mol Catal A,2015, 398: 275

    43. [43]

      [43] Ma X T, Lu X H, Wei C C, Zhao H J, Zhan Z S, Zhou H D, Xia Q H. Catal Commun, 2015, 67: 98

  • 加载中
    1. [1]

      Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

    2. [2]

      Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184

    3. [3]

      Tao Wen ,  Tao Zhang ,  Changguo Sun ,  Jinyu Liu . Preparation of Dess-Martin Reagent and Its Application in Oxidizing Cyclohexanol. University Chemistry, 2024, 39(5): 20-26. doi: 10.3866/PKU.DXHX202309055

    4. [4]

      Zhuoyan Lv ,  Yangming Ding ,  Leilei Kang ,  Lin Li ,  Xiao Yan Liu ,  Aiqin Wang ,  Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuOx/TiO2 Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015

    5. [5]

      Pei Li ,  Yuenan Zheng ,  Zhankai Liu ,  An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012

    6. [6]

      Junjie Zhang ,  Yue Wang ,  Qiuhan Wu ,  Ruquan Shen ,  Han Liu ,  Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084

    7. [7]

      Guojie Xu ,  Fang Yu ,  Yunxia Wang ,  Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060

    8. [8]

      Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014

    9. [9]

      Keweiyang Zhang ,  Zihan Fan ,  Liyuan Xiao ,  Haitao Long ,  Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084

    10. [10]

      Chi Li ,  Jichao Wan ,  Qiyu Long ,  Hui Lv ,  Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016

    11. [11]

      Hongling Yuan ,  Jialin Xie ,  Jiawei Wang ,  Jixiang Zhao ,  Jiayan Liu ,  Qing Feng ,  Wei Qi ,  Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041

    12. [12]

      Hong Zheng ,  Xin Peng ,  Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058

    13. [13]

      Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291

    14. [14]

      Shanghua Li ,  Malin Li ,  Xiwen Chi ,  Xin Yin ,  Zhaodi Luo ,  Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003

    15. [15]

      Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363

    16. [16]

      Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275

    17. [17]

      Zhanhui Yang ,  Jiaxi Xu . (m+n+…) or [m+n+…]cycloaddition?. University Chemistry, 2025, 40(3): 387-389. doi: 10.12461/PKU.DXHX202406032

    18. [18]

      Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382

    19. [19]

      Conghao Shi ,  Ranran Wang ,  Juli Jiang ,  Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034

    20. [20]

      Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(293)
  • HTML views(4)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return