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Citation: Maryam Moosavifar, Alieh Navid Arbat, Zolfaghar Rezvani, Kamellia Nejati. Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Cox/Mny) as nanocomposite catalysts for the epoxidation of cyclohexene[J]. Chinese Journal of Catalysis, ;2015, 36(10): 1719-1725. doi: 10.1016/S1872-2067(15)60908-1 shu

Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Cox/Mny) as nanocomposite catalysts for the epoxidation of cyclohexene

  • 1.

    a Department of Chemistry, Faculty of Science, University of Maragheh, Maragheh, Iran;

  • Corresponding author: Maryam Moosavifar, 
  • Received Date: 4 April 2015
    Available Online: 19 May 2015

  • Trinuclear metal clusters of Co, Mn and mixtures of Co/Mn including [Mn3(O)(CH3COO)6-(py)3]-Y, [Co3(O)(CH3COO)6-(py)3], [Co2Mn(O)(CH3COO)6-(py)3]-Y and [CoMn2(O)(CH3COO)6-(py)3]-Y] were prepared inside the nanocage of dealuminated Y zeolite by the template synthesis method. These catalysts were characterized by Fourier transform infrared, Ultraviolet-visible, field scanning electron microscopy, X-ray diffraction and atomic absorption spectroscopy. The encapsulated metal clusters showed good catalytic activity in the epoxidation of cyclohexene with H2O2/O2. Epoxide yields were 82.5% to 90.7%. NaBr was used as a promoter for the oxidation. The homonuclear metal clusters showed higher catalytic activity than the others and the highest efficiency was with the Mn3(O)-DAZY compound. The catalytic activity order was Mn3(O)-DAZY > Co3(O)-DAZY > Mn2Co(O)-DAZY > MnCo2(O)-DAZY.
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