Citation: Jia-de Li, Chang-lin Yu, Wen Fang, Li-hua Zhu, Wan-qin Zhou, Qi-zhe Fan. Preparation, characterization and photocatalytic performance of heterostructured AgCl/Bi₂WO₆ microspheres[J]. Chinese Journal of Catalysis, ;2015, 36(7): 987-993. doi: 10.1016/S1872-2067(15)60849-X shu

Preparation, characterization and photocatalytic performance of heterostructured AgCl/Bi₂WO₆ microspheres

Jia-de Li ^a ,
Chang-lin Yu ^a,, ,
Wen Fang ^a,b ,
Li-hua Zhu ^a ,
Wan-qin Zhou ^a ,
Qi-zhe Fan ^a

1.
a School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Jiangxi, Ganzhou 341000, Jiangxi, China;

Corresponding author: Chang-lin Yu,
Received Date: 25 February 2015
Available Online: 27 March 2015
Fund Project: 国家自然科学基金(21067004, 21263005) (21067004, 21263005) 江西省自然科学基金青年科学基金计划(20133BAB21003) (20133BAB21003) 江西省教育厅高等学校科技落地计划项目(KJLD14046) (KJLD14046) 江西省青年科学家培养项目(20122BCB23015) (20122BCB23015) 江西省远航工程, 江西省研究生创新资金项目(3104000089, 3104100013) (3104000089, 3104100013) 江西理工大学研究生创新资金项目(104100039). (104100039)

Bi₂WO₆ microspheres with a diameter of 1.5-2 μm were prepared by a hydrothermal method, and then coated with different contents of AgCl to form heterostructured AgCl/Bi₂WO₆ microspheres. The prepared Bi₂WO₆ and AgCl/Bi₂WO₆ photocatalysts were characterized by X-ray diffraction, N₂ physical adsorption, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy. The photocatalytic activity of the catalysts was evaluated by photocatalytic degradation of rhodamine B under ultraviolet and visible light irradiation. Results showed that the deposition of AgCl had no obvious effect on the light absorption and surface properties of Bi₂WO₆. However, the heterostructured AgCl/Bi₂WO₆ photocatalysts exhibited considerably higher activity than the pure AgCl and Bi₂WO₆ catalysts. With the optimal AgCl content of 20 wt%, the photocatalytic activity of the heterostructured AgCl/Bi₂WO₆ catalyst was increased under both ultraviolet and visible light compared with that of Bi₂WO₆. The main reason for the enhanced photocatalytic activity is attributed to the formation of AgCl/Bi₂WO₆ heterostructures effectively suppressing the recombination of photogenerated electrons and holes.
- Microsphere,
- Silver chloride,
- Bismuth tungstate,
- Heterostructure,
- Photocatalysis,
- Rhodamine B
1. [1]
  [1] He R A, Cao Sh W, Zhou P, Yu J G. Chin J Catal (赫荣安, 曹少文, 周鹏, 余家国. 催化学报), 2014, 35: 989
2. [2]
  [2] Yu C L, Wei L F, Zhou W Q, Chen J C, Fan Q Z, Liu H. Appl Sur Sci, 2014, 319: 312
3. [3]
  [3] Bian Z F, Cao F L, Zhu J, Li H X. Environ Sci Technol, 2015, 49: 2418
4. [4]
  [4] Xu D F, Cheng B, Cao S W, Yu J G. Appl Catal B, 2015, 164: 380
5. [5]
  [5] Yu C L, Chen J C, Cao F F, Li X, Fan Q Z, Yu J C, Wei L F. Chin J Catal (余长林, 陈建钗, 操芳芳, 李鑫, 樊启哲, Yu J C, 魏龙福. 催化学报), 2013, 34:385
6. [6]
  [6] Wang P, Ming T S, Wang G H, Wang X F, Yu H G, Yu J G. J Mol Catal A, 2014, 381: 114
7. [7]
  [7] Tang J W, Zou Z G, Ye J H. Catal Lett, 2004, 92: 53
8. [8]
  [8] Liu Y M, Lv H, Hu J Y, Li Z J. Mater Lett, 2015,139: 401
9. [9]
  [9] Liu L, Wang Y F, An W J, Hu J S, Cui W Q, Liang Y H. J Mol Catal A, 2014, 394: 309
10. [10]
  [10] Zhao G, Liu S W, Lu Q F, Xu F X, Sun H Y. J Alloys Compd, 2013, 578: 12
11. [11]
  [11] Li Y, Liu J, Huang X, Li G. Cryst Growth Des, 2007, 7: 1350
12. [12]
  [12] Liu Y, Wang W M, Fu Z Y, Wang H, Wang Y C, Zhang J Y. J Inorg Mater (刘瑛, 王为民, 傅正义, 王皓, 王玉成, 张金咏. 无机材料学报), 2011, 26: 1169
13. [13]
  [13] Zhang L W, Wang Y J, Cheng H Y, Yao W Q, Zhu Y F. Adv Mater. 2009, 21: 1286
14. [14]
  [14] Zhang L S, Wang W Z, Zhou L, Xu H L. Small, 2007, 3: 1618
15. [15]
  [15] Yu C L, Cao F F, Li X, Li G, Xie Y, Yu J C, Shu Q, Fan Q Z, Chen J C. Chem Eng J, 2013, 219: 86
16. [16]
  [16] Li X Z, Liu H, Cheng L F, Tong H J. Environ Sci Technol, 2003, 37: 3989
17. [17]
  [17] Yu C L, Yang K, Xie Y, Fan Q Z, Yu J C, Shu Q, Wang C Y. Nanoscale, 2013, 5: 2142
18. [18]
  [18] Yang J H, Wang D E, Han H X, Li C. Acc Chem Res, 2013, 46: 1900
19. [19]
  [19] Yu C L, Fan C F, Yu J C, Zhou W Q, Yang K. Mater Res Bull, 2011, 46: 140
20. [20]
  [20] Yu C L, Yang K, Shu Q, Yu J C, Cao F F, Li X. Chin J Catal (余长林, 杨凯, 舒庆, Yu J C, 操芳芳, 李鑫. 催化学报), 2011, 32: 555
21. [21]
  [21] Yu C L, Li G, Kumar S, Yang K, Jin R C. Adv Mater, 2014, 26: 892
22. [22]
  [22] Gao L, Zheng S, Zhang Q H. Nano TiO₂ Photocatalytic Materials and Their Application. Beijing: Chem Ind Press, 2002. 110
23. [23]
  [23] Yu C L, Zhou W Q, Yu J C, Liu H, Wei L F. Chin J Catal (余长林, 周晚琴, 余济美, 刘鸿, 魏龙福. 催化学报), 2014, 35: 1609
24. [24]
  [24] Dai G P, Yu J G, Liu G. J Phys Chem C, 2011, 115: 7339
25. [25]
  [25] Fu H B, Zhang L W, Yao W Q, Zhu Y F. Appl Catal B, 2006, 66: 100
26. [26]
  [26] Zhu S B, Xu T G, Fu H B, Zhao J C, Zhu Y F. Environ Sci Technol, 2007, 41: 6234
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Preparation, characterization and photocatalytic performance of heterostructured AgCl/Bi2WO6 microspheres

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Preparation, characterization and photocatalytic performance of heterostructured AgCl/Bi₂WO₆ microspheres