Citation: Nianzhe Li, Yuan Gao, Xinxin Zhang, Zhanjun Yu, Lei Shi, Qi Sun. Oxidation of styrene to benzaldehyde by p-toluenesulfonic acid using hydrogen peroxide in the presence of activated carbon[J]. Chinese Journal of Catalysis, ;2015, 36(5): 721-727. doi: 10.1016/S1872-2067(14)60314-4 shu

Oxidation of styrene to benzaldehyde by p-toluenesulfonic acid using hydrogen peroxide in the presence of activated carbon

1.
Institute of Chemistry for Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning, China

Corresponding author: Qi Sun,
Received Date: 25 December 2014
Available Online: 30 January 2015
Fund Project: 国家自然科学基金(21173110). (21173110)

The selective oxidation of styrene to benzaldehyde catalyzed by p-toluenesulfonic acid (p-TsOH) in the presence of activated carbon (AC) was investigated with H₂O₂ as the oxidant. The reaction parameters of reaction time, temperature, catalyst mass, and styrene/H₂O₂ molar ratios were evaluated. A strong promoting effect of AC on the p-TsOH/H₂O₂ system was observed. The appropriate ratio and amounts of AC and p-TsOH were an important factor. The acidity of p-TsOH does not play a significant role. p-TsOH reacted with H₂O₂ by a non-radical process to oxidize styrene. The function of the AC was to activate H₂O₂and to help the p-TsOH/H₂O₂ system in styrene oxidation. The reduction of oxygen containing groups (-OH, -COOH) on AC by a high temperature treatment or introduction of -SO₃H groups onto AC affected the styrene conversion. The -SO₃H groups were more effective than the oxygen-containing groups on the AC in promoting styrene oxidation.
- Styrene,
- Hydrogen peroxide,
- p-Toluenesulfonic acid,
- Activated carbon,
- Oxidation
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