Citation: Mahmoud. Abd, El Aleem. Ali, Ali. El-Remaily. Bismuth triflate: A highly efficient catalyst for the synthesis of bio-active coumarin compounds via one-pot multi-componentreaction[J]. Chinese Journal of Catalysis, ;2015, 36(7): 1124-1130. doi: 10.1016/S1872-2067(14)60308-9 shu

Bismuth triflate: A highly efficient catalyst for the synthesis of bio-active coumarin compounds via one-pot multi-componentreaction

1.
Department of Chemistry, Faculty of Science, Sohag University- 82524, Sohag, Egypt

Corresponding author: Ali. El-Remaily,
Received Date: 9 January 2015
Available Online: 2 February 2015

A series of coumarin-chalcone hybrid compounds and coumarins linked to pyrazoline was synthesized in good yield and short time using a simple and efficient method. This method involved the one-pot reaction of salicylaldehyde, an α-ketoester and an aromatic aldehyde (in the case of the coumarin-chalcone derivatives) in addition to hydrazine hydrate (in the case of the pyrazolyl coumarins) in the presence of a catalytic amount of bismuth triflate [Bi(OTf)₃, 5 mol%]. The synthesized compounds showed scavenging activity towards the free radical 2,2-diphenyl-1-picrylhydrazyl. All compounds were characterized using IR, ¹H NMR and ¹³C NMR spectroscopy.
- Coumarin,
- Chalcone,
- Pyrazoline,
- One-pot multi-component reaction,
- Salicylaldehyde,
- α-Ketoester,
- Bismuth triflate [Bi(OTf)₃]
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沈阳化工大学材料科学与工程学院沈阳 110142