Citation: Qiuhua Zhu, Hongwei Cheng, Xingli Zou, Xionggang Lu, Qian Xu, Zhongfu Zhou. Synthesis, characterization, and catalytic performance of La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite catalysts in dry reforming of coke oven gas[J]. Chinese Journal of Catalysis, ;2015, 36(7): 915-924. doi: 10.1016/S1872-2067(14)60303-X shu

Synthesis, characterization, and catalytic performance of La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite catalysts in dry reforming of coke oven gas

Qiuhua Zhu ^a ,
Hongwei Cheng ^a,, ,
Xingli Zou ^a ,
Xionggang Lu ^a,, ,
Qian Xu ^a ,
Zhongfu Zhou ^a,b

1.
a Shanghai Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University, Shanghai 200072, China;

Corresponding author: Hongwei Cheng, Xionggang Lu,
Received Date: 23 December 2014
Available Online: 28 January 2015
Fund Project: 国家自然科学基金(51474145) (51474145) 国家杰出青年科学基金(51225401) (51225401) 上海市青年科技启明星计划(15QA1402100) (15QA1402100) 上海市教育委员会科研创新项目(14YZ013). (14YZ013)

The dry reforming of coke oven gas (COG) to produce syngas was performed over La_0.6Sr_0.4Ni_xCo_1-xO₃ catalysts in a fixed-bed reactor at 800 ℃. These perovskite-type oxides were synthesized using a sol-gel method and characterized using X-ray diffraction (XRD), N₂ adsorption-desorption, temperature-programmed reduction of H₂, scanning electron microscopy, transmission electron microscopy, and thermogravimetry-differential scanning calorimetry. XRD results showed that the La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite-type oxides formed quaternary solid solutions. The effects of the degree of Ni substitution (x) and the catalyst calcination temperature on the dry reforming of COG were investigated. XRD analysis of the tested catalysts showed the formation of Ni⁰, Co⁰, and La₂O₂CO₃, of which the latter is the main active phase responsible for the high activity and stability, and the suppression of coke formation under severe reaction conditions. COG rich in H₂ can also reduce the formation of carbon deposits by inhibiting CH₄ decomposition.
- Syngas,
- Catalytic activity,
- Perovskite,
- Dry reforming,
- Coke oven gas,
- Carbon deposit
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, characterization, and catalytic performance of La0.6Sr0.4NixCo1-xO3 perovskite catalysts in dry reforming of coke oven gas

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通讯作者: 陈斌, bchen63@163.com

Synthesis, characterization, and catalytic performance of La_0.6Sr_0.4Ni_xCo_1-xO₃ perovskite catalysts in dry reforming of coke oven gas