Citation: Pingjing Chang, Haiyang Cheng, Weiwei Lin, Xiaoru Li, Fengyu Zhao. A stable and active Ag_xS crystal preparation and its performance as photocatalyst[J]. Chinese Journal of Catalysis, ;2015, 36(4): 564-571. doi: 10.1016/S1872-2067(14)60288-6 shu

A stable and active Ag_xS crystal preparation and its performance as photocatalyst

Pingjing Chang ^a,b,c ,
Haiyang Cheng ^a,b ,
Weiwei Lin ^a,b ,
Xiaoru Li ^a,b,c ,
Fengyu Zhao ^a,b,,

1.
a State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, Jilin, China;

Corresponding author: Fengyu Zhao,
Received Date: 23 November 2014
Available Online: 8 January 2015
Fund Project: 国家自然科学基金(21273222). (21273222)

Ag_xS crystals were synthesized via hydrothermal (Ag_xS-H) and in situ ion-exchange (Ag_xS-IE) methods. The samples were characterized by scanning electron microscopy, X-ray diffraction, ultraviolet-visible-near infrared absorption spectroscopy, N₂ adsorption-desorption, X-ray photoelectron spectroscopy and surface photovoltage measurements. The photocatalytic performance was investigated for the decomposition of methyl blue (MB) under visible light irradiation (λ ≥ 420 nm). The Ag_xS-H had smaller particles, wider band gap and weaker recombination of photoinduced charges than Ag_xS-IE, resulting in a higher photocatalytic activity. Moreover, Ag_xS-H was stable, and could be reused five times without loss of photocatalytic activity. Additionally, a possible pathway for the photocatalytic degradation of MB over Ag_xS has been proposed, that MB was oxidized mainly by hydroxyl radicals and partly via electron holes generated in the Ag_xS. Ag_xS-H is an efficient photocatalyst and has great potential for the degradation of harmful organic dyes in wastewater.
- Silver sulfide,
- Visible light irradiation,
- Photocatalytic degradation,
- Organic pollutants,
- Band gap
1. [1]
  [1] Hou Y, Li X Y, Zhao Q D, Chen G H, Raston C L. Environ Sci Technol, 2012, 46: 4042
2. [2]
  [2] Shannon M A, Bohn P W, Elimelech M, Georgiadis J G, Marinas B J, Mayes A M. Nature, 2008, 452: 301
3. [3]
  [3] Meshko V, Markovska L, Mincheva M, Rodrigues A E. Water Res, 2001, 35: 3357
4. [4]
  [4] Cooper P. J Soc Dyers Colour, 1993, 109: 97
5. [5]
  [5] Patil S S, Shinde V M. Environ Sci Technol, 1988, 22: 1160
6. [6]
  [6] Moore A T, Vira A, Fogel S. Environ Sci Technol, 1989, 23:403
7. [7]
  [7] Correia V M, Stephenson T, Judd S J. Environ Technol, 1994, 15: 917
8. [8]
  [8] Arslan I, Balcioglu I A. Dyes Pigments, 1999, 43: 95
9. [9]
  [9] Wu F, Deng N S, Zuo Y G. Chemosphere, 1999, 39: 2079
10. [10]
  [10] Kang S F, Liao C H, Po S T. Chemosphere, 2000, 41: 1287
11. [11]
  [11] Balanosky E, Fernandez J, Kiwi J, Lopez A. Water Sci Technol, 1999, 40: 417
12. [12]
  [12] Arslan I, Balcioglu I A, Tuhkanen T. Environ Technol, 1999, 20: 921
13. [13]
  [13] Ince N H, Gonenc D T. Environ Technol, 1997, 18: 179
14. [14]
  [14] Kuo W S, Ho P H. Chemosphere, 2001, 45: 77
15. [15]
  [15] Zhang F L, Zhao J C, Shen T, Hidaka H, Pelizzetti E, Serpone N. Appl Catal B, 1998, 15: 147
16. [16]
  [16] Qu P, Zhao J C, Shen T, Hidaka H. J Mol Catal A, 1998, 129: 257
17. [17]
  [17] Galindo C, Jacques P, Kalt A. Chemosphere, 2001, 45: 997
18. [18]
  [18] Tang W Z, An H. Chemosphere, 1995, 31: 4157
19. [19]
  [19] Konstantinou I K, Albanis T A. Appl Catal B, 2004, 49: 1
20. [20]
  [20] Pelaez M, Nolan N T, Pillai S C, Seery M K, Falaras P, Kontos A G, Dunlop P S M, Hamilton J W J, Byrne J A, O'Shea K, Entezari M H, Dionysiou D D. Appl Catal B, 2012, 125: 331
21. [21]
  [21] Chong M N, Jin B, Chow C W K, Saint C. Water Res, 2010, 44: 2997
22. [22]
  [22] Wu P G, Xie R C, Imlay J A, Shang J K. Appl Catal B, 2009, 88: 576
23. [23]
  [23] Rizzo L, Sannino D, Vaiano V, Sacco O, Scarpa A, Pietrogiacomi D. Appl Catal B, 2014, 144:369
24. [24]
  [24] Chen X, Mao S S. Chem Rev, 2007, 107: 2891
25. [25]
  [25] Fujishima A, Rao T N, Tryk D A. J Photochem Photobiol C, 2000, 1: 1
26. [26]
  [26] Tong T Z, Zhang J L, Tian B Z, Chen F, He D N. J Hazard Mater, 2008, 155: 572
27. [27]
  [27] Tian B Z, Li C Z, Gu F, Jiang H B, Hu Y J, Zhang J L. Chem Eng J, 2009, 151: 220
28. [28]
  [28] Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y. Science, 2001, 293: 269
29. [29]
  [29] Niu Y X, Xing M Y, Tian B Z, Zhang J L. Appl Catal B, 2012, 115: 253
30. [30]
  [30] Zhao W, Ma W H, Chen C C, Zhao J C, Shuai Z G. J Am Chem Soc, 2004, 126: 4782
31. [31]
  [31] Bae E Y, Choi W Y, Park J W, Shin H S, Kim S B, Lee J S. J Phy Chem B, 2004, 108: 14093
32. [32]
  [32] Zou W W, Zhang J L, Chen F. Mater Lett, 2010, 64: 1710
33. [33]
  [33] Xie Y, Heo S H, Kim Y N, Yoo S H, Cho S O. Nanotechnology, 2010, 21: 015703
34. [34]
  [34] Neves M C, Nogueira J M F, Trindade T, Mendonca M H, Pereira M I, Monteiro O C. J Photochem Photobiol A, 2009, 204: 168
35. [35]
  [35] Hwang I, Seol M, Kim H, Yong K. Appl Phys Lett, 2013, 103: 023902
36. [36]
  [36] Yang W L, Zhang L, Hu Y, Zhong Y J, Wu H B, Lou X W. Angew Chem Int Ed, 2012, 51: 11501
37. [37]
  [37] Xing C S, Zhang Y, Wu Z D, Jiang D L, Chen M. Dalton Trans, 2014, 43: 2772
38. [38]
  [38] Smart R S C, Skinner W M, Gerson A R. Surf Interface Anal, 1999, 28:101
39. [39]
  [39] Chen Z, Liu S Q, Yang M Q, Xu Y J. ACS Appl Mater Interfaces, 2013, 5: 4309
40. [40]
  [40] Bao N Z, Shen L M, Takata T, Domen K. Chem Mater, 2008, 20: 110
41. [41]
  [41] Butler M A, Ginley D S. J Electrochem Soc, 1978, 125: 228
42. [42]
  [42] Netherco A H. Phys Rev Lett, 1974, 33: 1088
43. [43]
  [43] Huxter V M, Mirkovic T, Nair P S, Scholes G D. Adv Mater, 2008, 20: 2439
44. [44]
  [44] Zhang Y J,Liu Y S, Li C Y, Chen X Y, Wang Q B. J Phys Chem C, 2014, 118: 4918
45. [45]
  [45] Zhang J K, Liu C L, Zhang X, Ke F, Han Y H, Peng G, Ma Y Z, Gao C X. Appl Phys Lett, 2013, 103: 082116
46. [46]
  [46] Zuo F, Wang L, Wu T, Zhang Z Y, Borchardt D, Feng P Y. J Am Chem Soc, 2010, 132: 11856
47. [47]
  [47] Wang H K, Dou K P, Teoh W Y, Zhan Y W, Hung T F, Zhang F H, Xu J Q, Zhang R Q, Rogach A L. Adv Funct Mater, 2013, 23: 4847
48. [48]
  [48] Hagfeldt A, Gratzel M. Chem Rev, 1995, 95: 49
49. [49]
  [49] Zhang X, Zhang L Z, Xie T F, Wang D J. J Phys Chem C, 2009, 113: 7371
50. [50]
  [50] Gross D, Mora-Seró I, Dittrich T, Belaidi A, Mauser C, Houtepen A J, Da Como E, Rogach A L, Feldmann J. J Am Chem Soc, 2010, 132: 5981
51. [51]
  [51] Fan H M, Jiang T F, Li H Y, Wang D J, Wang L L, Zhai J L, He D Q, Wang P, Xie T F. J Phys Chem C, 2012, 116: 2425
52. [52]
  [52] Khanchandani S, Srivastava P K, Kumar S, Ghosh S, Ganguli A K. Inorg Chem, 2014, 53: 8902
1. [1]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
2. [2]
  Jia Zhou , Huaying Zhong . Experimental Design of Computational Materials Science Combined with Machine Learning. University Chemistry, 2025, 40(3): 171-177. doi: 10.12461/PKU.DXHX202406004
3. [3]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
4. [4]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
5. [5]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
6. [6]
  Yurong Tang , Yunren Shi , Yi Xu , Bo Qin , Yanqin Xu , Yunfei Cai . Innovative Experiment and Course Transformation Practice of Visible-Light-Mediated Photocatalytic Synthesis of Isoquinolinone. University Chemistry, 2024, 39(5): 296-306. doi: 10.3866/PKU.DXHX202311087
7. [7]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
8. [8]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
9. [9]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
10. [10]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
11. [11]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
12. [12]
  .
  CCS Chemistry 综述推荐│绿色氧化新思路：光/电催化助力有机物高效升级
  . CCS Chemistry, 2025, 7(10.31635/ccschem.024.202405369): -.
13. [13]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
14. [14]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
15. [15]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
16. [16]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
17. [17]
  Weina Wang , Lixia Feng , Fengyi Liu , Wenliang Wang . Computational Chemistry Experiments in Facilitating the Study of Organic Reaction Mechanism: A Case Study of Electrophilic Addition of HCl to Asymmetric Alkenes. University Chemistry, 2025, 40(3): 206-214. doi: 10.12461/PKU.DXHX202407022
18. [18]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
19. [19]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
20. [20]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017

Get Citation

PDF

XML

Metrics

PDF Downloads(280)
Abstract views(483)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A stable and active AgxS crystal preparation and its performance as photocatalyst

Metrics

通讯作者: 陈斌, bchen63@163.com

A stable and active Ag_xS crystal preparation and its performance as photocatalyst