Citation: Vasko Idakiev, Dimitar Dimitrov, Tatyana Tabakova, Krasimir Ivanov, Zhong-Yong Yuan, Bao-Lian Su. Catalytic abatement of CO and volatile organic compounds in waste gases by gold catalysts supported on ceria-modified mesoporous titania and zirconia[J]. Chinese Journal of Catalysis, ;2015, 36(4): 579-587. doi: 10.1016/S1872-2067(14)60283-7 shu

Catalytic abatement of CO and volatile organic compounds in waste gases by gold catalysts supported on ceria-modified mesoporous titania and zirconia

1.
a Institute of Catalysis, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria;

Corresponding author: Vasko Idakiev,
Received Date: 17 November 2014
Available Online: 5 January 2015

Mesoporous oxides TiO₂ and ZrO₂, synthesized by surfactant templating via a neutral C₁₃(EO)₆-Zr(OC₃H₇)₄ assembly pathway, and ceria-modified TiO₂ and ZrO₂, prepared by a deposition-precipitation (DP) method, featuring high surface areas and uniform pore size distributions were used as supports for gold catalysts. The supported gold catalysts were assessed for the catalytic abatement of air pollutants, i.e., CO, CH₃OH, and (CH₃)₂O. The gold was supported on the mesoporous oxides by a DP method. The supports and catalysts were characterized by powder X-ray diffraction, high-resolution transmission electron microscopy, N₂ adsorption-desorption analysis, and temperature-programmed reduction technique. A high degree of synergistic interaction between ceria and mesoporous ZrO₂ and TiO₂ as well as a positive modification of the structural and catalytic properties by ceria was observed. The ceria additive interacts with the mesoporous oxides and induces a strong effect on the reducibility of the supports. The catalytic behavior of the catalysts was discussed to determine the role of the ceria modifying additive and possible interaction between the gold nanoparticles and ceria-mesoporous oxide supports. The gold catalysts supported on ceria-modified mesoporous ZrO₂ displayed superior catalytic activity (~100% conversion of CO at 10 ℃ and CH₃OH at 60 ℃). The high catalytic activity can be attributed to the ability of the support to assist oxygen vacancies formation. The studies indicate that the ceria-modified mesoporous oxide supports have potential as supports for gold-based catalysts.
- Gold catalyst,
- Mesoporous oxide,
- Carbon monoxide,
- Oxidation,
- Methanol dimethylether,
- Volatile organic compound abatement
1. [1]
  [1] Vieira Soares A P, Farinha Portela M, Kiennemann A. Catal Commun, 2001, 2: 159
2. [2]
  [2] Tatibouët J M. Appl Catal A, 1997, 148: 213
3. [3]
  [3] Armor N. Res Chem Intermed, 1998, 24: 105
4. [4]
  [4] Guczi L, Borko L, Schay Z. Stud Surf Sci Catal, 1998, 113: 69
5. [5]
  [5] Imamura S. Ind Eng Chem Res, 1999, 38: 1743
6. [6]
  [6] Zwinkels M F M, Jaras S G, Menon P G, Griffin T A. Catal Rev-Sci Eng, 1993, 35: 319
7. [7]
  [7] Liotta L F. Appl Catal B, 2010, 100: 403
8. [8]
  [8] Santos V P, Carabineiro S A C, Tavares P B, Pereira M F R, Órfão J J M, Figueiredo J L. Appl Catal B, 2010, 99: 198
9. [9]
  [9] Tang X L, Zhang B C, Li Y, Xu Y D, Xin Q, Shen W J. Catal Today, 2004, 93-95: 191
10. [10]
  [10] Mechandjiev D R, Dimitrova P G, Tzolovski I A, Raevski A B. WO Patent 2003061821. 2003
11. [11]
  [11] Scirè S, Liotta L F. Appl Catal B, 2012, 125: 222
12. [12]
  [12] Barakat T, Rooke J C, Genty E, Cousin R, Siffert S, Su B L. Energy Environ Sci, 2013, 6: 371
13. [13]
  [13] Haruta M, Ueda A, Tsubota S, Torres Sanchez R M. Catal Today, 1996, 29: 443
14. [14]
  [14] Petrov L A. Stud Surf Sci Catal, 2000, 130: 2345
15. [15]
  [15] Wang C T, Ro S H. Mater Chem Phys, 2007, 101: 41
16. [16]
  [16] Bonelli R, Albonetti S, Morandi V, Ortolani L, Riccobene P M, Scirè S, Zacchini S. Appl Catal A, 2011, 395: 10
17. [17]
  [17] Li W B, Wang J X, Gong H. Catal Today, 2009, 148: 81
18. [18]
  [18] Delimaris D, Ioannides T. Appl Catal B, 2009, 89: 295
19. [19]
  [19] Liotta L F, Ousmane M, Di Carlo G, Pantaleo G, Deganello G, Boreave A, Giroir-Fendler A. Catal Lett, 2009, 127: 270
20. [20]
  [20] Delimaris D, Ioannides T. Appl Catal B, 2008, 84: 303
21. [21]
  [21] Gutierrez-Ortiz J I, De Rivas B, Lopez-Fonseca R, Gonzalez-Velasco J R. Appl Catal B, 2006, 65: 191
22. [22]
  [22] Tabakova T, Dimitrov D, Manzoli M, Vindigni F, Petrova P, Ilieva L, Zanella R, Ivanov K. Catal Commun, 2013, 35: 51
23. [23]
  [23] Idakiev V, Ilieva L, Andreeva D, Blin J L, Gigot L, Su B L. Appl Catal A, 2003, 243: 25
24. [24]
  [24] Ousmane M, Liotta L F, Pantaleo G, Venezia A M, Di Carlo G, Aouine M, Retailleau L, Giroir-Fendler A. Catal Today, 2011, 176: 7
25. [25]
  [25] Zhang Y B, Shen Y N, Yang X Z, Sheng S S, Wang T, Adebajo M F, Zhu H Y. J Mol Catal A, 2010, 316: 100
26. [26]
  [26] Ying F, Wang S J, Au C T, Lai S Y. Microporous Mesoporous Mater, 2011, 142: 308
27. [27]
  [27] Gennequin C, Lamallem M, Cousin R, Siffert S, Aissi F, Aboukais A. Catal Today, 2007, 122: 301
28. [28]
  [28] Gennequin C, Lamallem M, Cousin R, Siffert S, Idakiev V, Tabakova T, Aboukaıs A, Su B L. J Mater Sci, 2009, 44: 6654
29. [29]
  [29] Idakiev V, Tabakova T, Tenchev K, Yuan Z Y, Ren T Z, Su B L. Catal Today, 2007, 128: 223
30. [30]
  [30] Idakiev V, Tabakova T, Naydenov A, Yuan Z Y, Su B L. Appl Catal B, 2006, 63: 178
31. [31]
  [31] Barret E P, Joyner L G, Halenda P P. J Am Chem Soc, 1951, 73: 373
32. [32]
  [32] Brunauer S, Emmett P H, Teller E. J Am Chem Soc, 1938, 60: 309
33. [33]
  [33] Idakiev V, Tabakova T, Tenchev K, Yuan Z Y, Ren T Z, Su B L. J Porous Mater, 2012, 19: 15
34. [34]
  [34] Del Monte F, Larsen W, Mackenzie J D. J Am Ceram Soc, 2000, 83: 1506
35. [35]
  [35] Brunauer S, Deming L S, Deming W E, Teller E. J Am Chem Soc, 1940, 62: 1723
36. [36]
  [36] Blin J L, Flamant R, Su B L. Int J Inorg Mater, 2001, 3: 959
37. [37]
  [37] Blin J L, Léonard A, Yuan Z Y, Gigot L, Vantomme A, Cheetham A K, Su B L. Angew Chem Int Ed, 2003, 42: 2872
38. [38]
  [38] Idakiev V, Tabakova T, Yuan Z Y, Su B L. Appl Catal A, 2004, 270: 135
39. [39]
  [39] Yao H C, Yu Yao Y F. J Catal, 1984, 86: 254
40. [40]
  [40] Andreeva D, Idakiev V, Tabakova T, Ilieva L, Falaras P, Bourlinos A, Travlos A. Catal Today, 2002, 72: 51
1. [1]
  Gongcheng Ma , Qihang Ding , Yuding Zhang , Yue Wang , Jingjing Xiang , Mingle Li , Qi Zhao , Saipeng Huang , Ping Gong , Jong Seung Kim . Palladium-free chemoselective probe for in vivo fluorescence imaging of carbon monoxide. Chinese Chemical Letters, 2024, 35(9): 109293-. doi: 10.1016/j.cclet.2023.109293
2. [2]
  Xiaoxue Li , Hongwei Zhou , Rongrong Qian , Xu Zhang , Lei Yu . A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene. Chinese Chemical Letters, 2025, 36(3): 110036-. doi: 10.1016/j.cclet.2024.110036
3. [3]
  Xiujuan Wang , Yijie Wang , Luyun Cui , Wenqiang Gao , Xiao Li , Hong Liu , Weijia Zhou , Jingang Wang . Coordination-based synthesis of Fe single-atom anchored nitrogen-doped carbon nanofibrous membrane for CO₂ electroreduction with nearly 100% CO selectivity. Chinese Chemical Letters, 2024, 35(12): 110031-. doi: 10.1016/j.cclet.2024.110031
4. [4]
  Zhikang Wu , Guoyong Dai , Qi Li , Zheyu Wei , Shi Ru , Jianda Li , Hongli Jia , Dejin Zang , Mirjana Čolović , Yongge Wei . POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents. Chinese Chemical Letters, 2024, 35(8): 109061-. doi: 10.1016/j.cclet.2023.109061
5. [5]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
6. [6]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847
7. [7]
  Wenjing Dai , Lan Luo , Zhen Yin . Interface reconstruction of hybrid oxide electrocatalysts for seawater oxidation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100442-100442. doi: 10.1016/j.cjsc.2024.100442
8. [8]
  Zeyu Jiang , Yadi Wang , Changwei Chen , Chi He . Progress and challenge of functional single-atom catalysts for the catalytic oxidation of volatile organic compounds. Chinese Chemical Letters, 2024, 35(9): 109400-. doi: 10.1016/j.cclet.2023.109400
9. [9]
  Jumei Zhang , Ziheng Zhang , Gang Li , Hongjin Qiao , Hua Xie , Ling Jiang . Ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes. Chinese Chemical Letters, 2025, 36(2): 110278-. doi: 10.1016/j.cclet.2024.110278
10. [10]
  Gang Hu , Chun Wang , Qinqin Wang , Mingyuan Zhu , Lihua Kang . The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein. Chinese Chemical Letters, 2025, 36(2): 110298-. doi: 10.1016/j.cclet.2024.110298
11. [11]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
12. [12]
  Chengcheng Xie , Chengyi Xiao , Hongshuo Niu , Guitao Feng , Weiwei Li . Mesoporous organic solar cells. Chinese Chemical Letters, 2024, 35(11): 109849-. doi: 10.1016/j.cclet.2024.109849
13. [13]
  Yuling Ma , Dongqing Liu , Tao Zhang , Chengjie Song , Dongmei Liu , Peizhi Wang , Wei Wang . Bimetallic composite carbon fiber with persulfate mediation for intercepting volatile organic compounds during solar interfacial evaporation. Chinese Chemical Letters, 2025, 36(3): 110000-. doi: 10.1016/j.cclet.2024.110000
14. [14]
  Yanling Yang , Zhenfa Ding , Huimin Wang , Jianhui Li , Yanping Zheng , Hongquan Guo , Li Zhang , Bing Yang , Qingqing Gu , Haifeng Xiong , Yifei Sun . Dynamic tracking of exsolved PdPt alloy/perovskite catalyst for efficient lean methane oxidation. Chinese Chemical Letters, 2024, 35(4): 108585-. doi: 10.1016/j.cclet.2023.108585
15. [15]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
16. [16]
  Meng Wang , Yan Zhang , Yunbo Yu , Wenpo Shan , Hong He . High-temperature calcination dramatically promotes the activity of Cs/Co/Ce-Sn catalyst for soot oxidation. Chinese Chemical Letters, 2025, 36(1): 109928-. doi: 10.1016/j.cclet.2024.109928
17. [17]
  Xinyi Hu , Riguang Zhang , Zhao Jiang . Depositing the PtNi nanoparticles on niobium oxide to enhance the activity and CO-tolerance for alkaline methanol electrooxidation. Chinese Journal of Structural Chemistry, 2023, 42(11): 100157-100157. doi: 10.1016/j.cjsc.2023.100157
18. [18]
  Huijuan Li , Zhu Wang , Jiagen Geng , Ruiping Song , Xiaoyin Liu , Chaochen Fu , Si Li . Current advances in UV-based advanced oxidation processes for the abatement of fluoroquinolone antibiotics in wastewater. Chinese Chemical Letters, 2025, 36(4): 110138-. doi: 10.1016/j.cclet.2024.110138
19. [19]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
20. [20]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166

Get Citation

PDF

XML

Metrics

PDF Downloads(250)
Abstract views(486)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142