Advanced Search

Citation: Yanpeng Pei, Yunjie Ding, Hejun Zhu, Hong Du. One-step production of C1-C18 alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO2[J]. Chinese Journal of Catalysis, ;2015, 36(3): 355-361. doi: 10.1016/S1872-2067(14)60252-7 shu

One-step production of C1-C18 alcohols via Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts: Promotional effect of modification by SiO2

  • 1.

    a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

  • Corresponding author: Yunjie Ding, 
  • Received Date: 13 September 2014
    Available Online: 12 November 2014

  • The promotional effect of SiO2 on the catalytic synthesis of mixed C1-C18 alcohols from syngas using the Fischer-Tropsch reaction over activated carbon-supported cobalt catalysts was investigated. X-ray diffraction, H2 temperature-programmed reduction, pulsed CO chemisorption and N2 physisorption techniques were all employed to assess the catalyst. Although the addition of SiO2 decreased the reducibility of the Co component, Co dispersion was significantly increased and its aggregation during reaction was inhibited, resulting in greatly enhanced reaction activity. Appropriate amounts of SiO2 also promoted the formation of Co2C, leading to an increased selectivity for C1-C18 alcohols. More importantly, the addition of SiO2 favored the formation of higher molecular mass alcohols (C6-C18) by suppressing Co reduction, thus producing an abundance of Co(II) species capable of facilitating CO insertion.
  • 加载中
    1. [1]

      [1] Khodakov A Y, Chu W, Fongarland P. Chem Rev, 2007, 107: 1692

    2. [2]

      [2] Torres Galvis H M, Bitter J H, Khare C B, Ruitenbeek M, Dugulan A I, de Jong K P. Science, 2012, 335: 835

    3. [3]

      [3] Fischer F, Tropsch H. Brennst Chem, 1923, 18: 274

    4. [4]

      [4] Li H L, Wang S G, Ling F X, Li J L. J Mol Catal A, 2006, 244: 33

    5. [5]

      [5] Anderson R B, Kölbel H, Ralek M. The Fischer-Tropsch Synthesis. Orland: Academic Press, 1984. 122

    6. [6]

      [6] Forzatti P, Tronconi E, Pasquon I. Catal Rev-Sci Eng, 1991, 33: 109

    7. [7]

      [7] Baker J E, Burch R, Hibble S J, Loader P K. Appl Catal A, 1990, 65: 281

    8. [8]

      [8] Yang X M, Wei Y, Su Y L, Zhou L P. Fuel Process Technol, 2010, 91: 1168

    9. [9]

      [9] Jiao G P, Ding Y J, Zhu H J, Li X M, Li J W, Lin R H, Dong W D, Gong L F, Pei Y P, Lu Y. Appl Catal A, 2009, 364: 137

    10. [10]

      [10] Pei Y P, Ding Y J, Zang J, Song X G, Dong W D, Zhu H J, Wang T, Chen W M. Chin J Catal (裴彦鹏, 丁云杰, 臧娟, 宋宪根, 董文达, 朱何俊, 王涛, 陈维苗. 催化学报), 2012, 33: 808

    11. [11]

      [11] Pei Y P, Ding Y J, Zang J, Song X G, Dong W D, Zhu H J, Wang T, Chen W M. Chin J Catal(裴彦鹏, 丁云杰, 臧娟, 宋宪根, 董文达, 朱何俊, 王涛, 陈维苗. 催化学报), 2013, 34: 1570

    12. [12]

      [12] Pei Y P, Ding Y J, Zhu H J, Zang J, Song X G, Dong W D, Wang T, Lu Y. Catal Lett, 2014, 144: 1433

    13. [13]

      [13] Dlamini H, Motjope T, Joorst G, Stegeter G, Mdleleni M. Catal Lett, 2002,78: 201

    14. [14]

      [14] Sun X Y, Zhang X J, Zhang Y, Tsubaki N. Appl Catal A, 2010, 377: 134

    15. [15]

      [15] Ma W P, Kugler E L, Dadyburjor D B. Energy Fuels, 2010, 24: 4099

    16. [16]

      [16] Bechara R, Balloy D, Dauphin J Y, Grimblot J. Chem Mater, 1999, 11: 1703

    17. [17]

      [17] Dimitrova P G, Mehandjiev D R. J Catal, 1994, 145: 356

    18. [18]

      [18] de Miguel S R, Romon-Martinez M C, Jablonski E L, Fierro J L G, Cazorla-Amoros D, Scelza O A. J Catal, 1999, 184: 514

    19. [19]

      [19] Díaz K, García V, Matos J. Fuel, 2007, 86: 1337

    20. [20]

      [20] Fan L, Yokota K, Fujimoto K. AIChE J, 1992, 38: 1639

    21. [21]

      [21] Xiong J M, Ding Y J, Wang T, Yan L, Chen W M, Zhu H J, Lu Y. Catal Lett, 2005, 102: 265

    22. [22]

      [22] Lebarbier V M, Mei D H, Kim D H, Andersen A, Male J L, Holladay J E, Rousseau R, Wang Y. J Phys Chem C, 2011, 115: 17440

    23. [23]

      [23] Lü Z P, Tang H D, Liu C L, Liu H Z. Chin J Catal (吕兆坡, 唐浩东, 刘采来, 刘化章. 催化学报), 2011, 32: 1250

    24. [24]

      [24] Visconti C G, Tronconi E, Lietti L, Zennaro R, Forzatti P. Chem Eng Sci, 2007, 62: 5338

    25. [25]

      [25] Kuipers E W, Scheper C, Wilson J H, Vinkenburg I H, Oosterbeek H. J Catal, 1996, 158: 288

    26. [26]

      [26] Bezemer G L, Bitter J H, Kuipers H P C E, Oosterbeek H, Holewijn J E, Xu X D, Kapteijn F, van Dillen A J, de Jong K P. J Am Chem Soc, 2006, 128: 3956

    27. [27]

      [27] den Breejen J P, Radstake P B, Bezemer G L, Bitter J H, Frøseth V, Holmen A, de Jong K P. J Am Chem Soc, 2009, 131: 7197

    28. [28]

      [28] Song D C, Li J L. J Mol Catal A, 2006, 247: 206

    29. [29]

      [29] Lögdberg S, Lualdi M, Järås S, Walmsley J C, Blekkan E A, Rytter E, Holmen A. J Catal, 2010, 274: 84

    30. [30]

      [30] Pei Y P, Ding Y J, Zhu H J, Zang J, Song X G, Dong W D, Wang T, Yan L, Lu Y. Reac Kinet Mech Catal, 2014, 111: 505

    31. [31]

      [31] de Aquino A D, Cobo A J G. Catal Today, 2001, 65: 209

    32. [32]

      [32] Balonek C M, Lillebo A H, Rane S, Rytter E, Schmidt L D, Holmen A. Catal Lett, 2010, 138: 8

    33. [33]

      [33] Ishida T, Yanagihara T, Liu X H, Ohashi H, Hamasaki A, Honma T, Oji H, Yokoyama T, Tokunaga M. Appl Catal A, 2013, 458: 145

  • 加载中
    1. [1]

      Zhiquan Zhang ,  Baker Rhimi ,  Zheyang Liu ,  Min Zhou ,  Guowei Deng ,  Wei Wei ,  Liang Mao ,  Huaming Li ,  Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO2 Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029

    2. [2]

      Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

    3. [3]

      Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH2 supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317

    4. [4]

      Xinhao Yan ,  Guoliang Hu ,  Ruixi Chen ,  Hongyu Liu ,  Qizhi Yao ,  Jiao Li ,  Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073

    5. [5]

      Xuejie Wang ,  Guoqing Cui ,  Congkai Wang ,  Yang Yang ,  Guiyuan Jiang ,  Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044

    6. [6]

      Caixia Lin ,  Zhaojiang Shi ,  Yi Yu ,  Jianfeng Yan ,  Keyin Ye ,  Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005

    7. [7]

      Hailian Tang ,  Siyuan Chen ,  Qiaoyun Liu ,  Guoyi Bai ,  Botao Qiao ,  Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004

    8. [8]

      Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V2O5/TiO2 catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

    9. [9]

      Juntao Yan ,  Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024

    10. [10]

      Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023

    11. [11]

      Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363

    12. [12]

      Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028

    13. [13]

      Jiapei Zou ,  Junyang Zhang ,  Xuming Wu ,  Cong Wei ,  Simin Fang ,  Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081

    14. [14]

      Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO2 reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409

    15. [15]

      Xue Dong ,  Xiaofu Sun ,  Shuaiqiang Jia ,  Shitao Han ,  Dawei Zhou ,  Ting Yao ,  Min Wang ,  Minghui Fang ,  Haihong Wu ,  Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO2制C2+产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012

    16. [16]

      Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382

    17. [17]

      Wei Zhong ,  Dan Zheng ,  Yuanxin Ou ,  Aiyun Meng ,  Yaorong Su . K原子掺杂高度面间结晶的g-C3N4光催化剂及其高效H2O2光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005

    18. [18]

      Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni3N supported Al-doped SrTiO3: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371

    19. [19]

      Guang Huang ,  Lei Li ,  Dingyi Zhang ,  Xingze Wang ,  Yugai Huang ,  Wenhui Liang ,  Zhifen Guo ,  Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051

    20. [20]

      Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043

Get Citation
PDF
XML
Metrics
  • PDF Downloads(204)
  • Abstract views(670)
  • HTML views(92)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return