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Citation: N. G. Grigor'eva, S. V. Bubennov, L. M. Khalilov, B. I. Kutepov. Dimerization of norbornene on zeolite catalysts[J]. Chinese Journal of Catalysis, ;2015, 36(3): 268-273. doi: 10.1016/S1872-2067(14)60251-5 shu

Dimerization of norbornene on zeolite catalysts

1.
Federal State Budget Institution of Science, Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation

Corresponding author: N. G. Grigor'eva,
Received Date: 5 September 2014
Available Online: 12 November 2014

The high activity and selectivity of H-Beta and H-ZSM-12 zeolites in the dimerization of norbornene was established. The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium, with a selectivity of dimer formation of 88%-98%. Four stereo-isomers of the bis-2,2'-norbornylidene structure were identified in the dimer fraction, with the (Z)-anti-bis-2,2'- norbornylidene prevailing over the others
- Zeolites,
- Norbornene,
- Dimerization,
- Bisnorbornylidenes
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