Citation: Luhua Jiang, Qiwen Tang, Jing Liu, Gongquan Sun. Elucidation of oxygen reduction reaction pathway on carbon-supported manganese oxides[J]. Chinese Journal of Catalysis, ;2015, 36(2): 175-180. doi: 10.1016/S1872-2067(14)60249-7 shu

Elucidation of oxygen reduction reaction pathway on carbon-supported manganese oxides

Luhua Jiang ^a,, ,
Qiwen Tang ^a,b ,
Jing Liu ^a,b ,
Gongquan Sun ^a,,

1.
a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Luhua Jiang, Gongquan Sun,
Received Date: 30 September 2014
Available Online: 10 November 2014
Fund Project: 中国科学院战略性先导科技专项(XDA09030104) (XDA09030104) 国家重点基础研究发展计划(973计划, 2012CB215500) (973计划, 2012CB215500) 国家自然科学基金(21033009) (21033009)

The oxygen reduction reaction (ORR) is a complex process. This is particularly the case for carbon-supported electrocatalysts in alkaline electrolytes, because carbon can catalyze the ORR via a two-electron transfer to generate hydroperoxide (HO₂^-), which subsequently undergoes either chemical decomposition to generate O₂ and OH^- (HODR) or electrochemical reduction to OH^- (HORR). In this study, we elucidated the ORR pathway on a series of carbon-supported manganese oxides, which have been extensively studied as electrocatalysts in alkaline electrolytes. A comparison of the turnover frequencies of the HODR and HORR showed that although an apparent four-electron transfer process was identified when the HO₂^- yield was measured using the rotating ring disk electrode technique, the real ORR pathway involved a two-electron transfer process to generate HO₂^-, with subsequent chemical decomposition of HO₂^-. These results will help us to understand the intrinsic catalytic behavior of carbon-supported transition-metal oxides for the ORR in alkaline electrolytes.
- Oxygen reduction reaction pathway,
- Alkaline electrolyte,
- Carbon-supported electrocatalyst
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