Citation: Barbara Villa-Marcos, Jianliang Xiao. Barbara Villa-Marcos, Jianliang Xiao[J]. Chinese Journal of Catalysis, ;2015, 36(1): 106-112. doi: 10.1016/S1872-2067(14)60246-1 shu

Barbara Villa-Marcos, Jianliang Xiao

Barbara Villa-Marcos ,
Jianliang Xiao ^,

1.
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK

Corresponding author: Jianliang Xiao,
Received Date: 12 September 2014
Available Online: 25 October 2014

A new protocol that enables asymmetric hydroaminomethylation of styrenes to afford chiral amines has been developed. Catalysed by an Rh-phosphine species and a chiral phosphoric acid, styrenes are converted into β-chiral amines with good enantioselectivities under syngas in the presence of an amine and Hantzsch ester. The reaction involves two key steps, hydroformylation and reductive amination, with the former catalysed by the Rh species whilst the latter by the phosphoric acid.
- Asymmetric hydroaminomethylation,
- Hydroformylation,
- Chiral amine,
- Metal catalysis,
- Organocatalysis
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沈阳化工大学材料科学与工程学院沈阳 110142