Citation: Xiaoming Zhang, Shengmei Lu, Mingmei Zhong, Yaopeng Zhao, Qihua Yang. Rh-PPh₃-polymer@mesosilica composite catalyst for the hydroformylation of 1-octene[J]. Chinese Journal of Catalysis, ;2015, 36(2): 168-174. doi: 10.1016/S1872-2067(14)60228-X shu

Rh-PPh₃-polymer@mesosilica composite catalyst for the hydroformylation of 1-octene

1.
a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Yaopeng Zhao, Qihua Yang,
Received Date: 25 July 2014
Available Online: 15 August 2014
Fund Project: 国家重点基础研究发展计划(973计划, 2010CB833300) (973计划, 2010CB833300) 国家自然科学基金(21203184). (21203184)

Rh-PPh₃-polymer@mesosilica composites were prepared by the polymerization of mixtures of divinylbenzene (DVB) and 4-vinyl-triphenylphosphine monomer in the nanopores of mesoporous silicas followed by coordination with Rh(acac)(CO)₂ (acac =acetylacetonate). These catalysts were characterized by XRD, N₂ sorption, TEM, FT-IR, and TG, and could efficiently catalyze the hydroformylation of 1-octene with higher activity than a pure polymer catalyst because of their high surface area and large pore volume, which were beneficial for the exposure of active sites and mass transport. Through the control of pore size and pore connectivity by using different mesoporous silica (MCM-41, SBA-15, and FDU-12), the activity and selectivity can be controlled. Rh-PPh₃-polymer@FDU-12 with a cage-like mesostrucuture showed lower activity but slightly higher selectivity than the catalyst with a 2-D hexagonal mesostructure (Rh-PPh₃-polymer@SBA-15 or Rh-PPh₃-polymer@MCM-41). By varying the polymer content in the nanopores of the mesosilica, the activity and selectivity (92%-96%) can also be tuned. The solid composite catalyst can be recycled without loss of activity, but a decrease in selectivity was observed.
- Rh-PPh₃-polymer@mesosilica composite,
- Heterogeneous catalysis,
- Hydroformylation reaction
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沈阳化工大学材料科学与工程学院沈阳 110142

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Rh-PPh₃-polymer@mesosilica composite catalyst for the hydroformylation of 1-octene