Citation: Andrzej Jablonski, Adam Lewera. Improving the efficiency of a direct ethanol fuel cell by a periodic load change[J]. Chinese Journal of Catalysis, ;2015, 36(4): 496-501. doi: 10.1016/S1872-2067(14)60226-6 shu

Improving the efficiency of a direct ethanol fuel cell by a periodic load change

Andrzej Jablonski ,
Adam Lewera ^,

1.
Department of Chemistry, University of Warsaw, ul. Pasteura 1, 02-093 Warsaw, Poland

Corresponding author: Adam Lewera,
Received Date: 20 July 2014
Available Online: 12 September 2014

We present a simple method to increase the efficiency of a direct ethanol fuel cell by a periodic modulation of the load (pulsed mode). The fuel cell was periodically short circuited with a resistor (1 Ω) for a few seconds (high load period) followed by a low load period of up to 100 s when the resistor was disconnected. The open circuit voltage (OCV) values before and after the short circuit of the cell showed an increase of up to 70 mV. The higher OCV was due to the oxidation and removal of strongly adsorbed CO during the electric short circuit when the electric potential of the anode was increased to be close to the cathode potential. The depoisoned anode surface was much more active directly after the short circuit. The slow decrease of the OCV observed after the short circuit was caused by the subsequent poisoning of the anode surface, which can be neutralized by another short circuit. In general, a stable increase in cell performance was obtained by repetition of the electric short circuit. The data showed that the pulse mode gave an increase in the power generated by the direct ethanol fuel cell by up to 51% and was 6% on average. It is anticipated that this mode of operation can be used also in different types of polymer electrolyte membrane fuel cells where CO poisoning is a problem, and after optimization of the parameters, a much higher gain in efficiency can be obtained.
- Ethanol electrooxidation,
- Electrocatalysis,
- Direct ethanol fuel cell,
- Polymer electrolyte membrane fuel cell,
- Platinum,
- Platinum-ruthenium
1. [1]
  [1] Song S Q, Tsiakaras P. Appl Catal B, 2006, 63: 187
2. [2]
  [2] Lamy C, Belgsir E M, Leger J M. J Appl Electrochem, 2001, 31: 799
3. [3]
  [3] Antolini E. J Power Sources, 2007, 170: 1
4. [4]
  [4] Zhou W J, Zhou Z H, Song S Q, Li W Z, Sun G Q, Tsiakaras P, Xin Q. Appl Catal B, 2003, 46: 273
5. [5]
  [5] Song S Q, Zhou W J, Zhou Z H, Jiang L H, Sun G Q, Xin Q, Leontidis V, Kontou S, Tsiakaras P. Int J Hydrogen Energy, 2005, 30: 995
6. [6]
  [6] Brouzgou A, Podias A, Tsiakaras P. J Appl Electrochem, 2013, 43: 119
7. [7]
  [7] Brouzgou A, Song S Q, Tsiakaras P. Appl Catal B, 2012, 127: 371
8. [8]
  [8] Nakagawa N, Ito Y, Tsujiguchi T, Ishitobi H. J Power Sources, 2014, 248: 330
9. [9]
  [9] Nakagawa N, Kaneda Y, Wagatsuma M, Tsujiguchi T. J Power Sources, 2012, 199: 103
10. [10]
  [10] Zhou W J, Song S Q, Li W Z, Sun G Q, Xin Q, Kontou S, Poulianitis K, Tsiakaras P. Solid State Ionics, 2004, 175: 797
11. [11]
  [11] Zhou W J, Li W Z, Song S Q, Zhou Z H, Jiang L H, Sun G Q, Xin Q, Poulianitis K, Kontou S, Tsiakaras P. J Power Sources, 2004, 131: 217
12. [12]
  [12] Lamy C, Rousseau S, Belgsir E M, Coutanceau C, Leger J M. Electrochim Acta, 2004, 49: 3901
13. [13]
  [13] Borup R, Meyers J, Pivovar B, Kim Y S, Mukundan R, Garland N, Myers D, Wilson M, Garzon F, Wood D, Zelenay P, More K, Stroh K, Zawodzinski T, Boncella J, McGrath J E, Inaba M, Miyatake K, Hori M, Ota K, Ogumi Z, Miyata S, Nishikata A, Siroma Z, Uchimoto Y, Yasuda K, Kimijima K I, Iwashita N. Chem Rev, 2007, 107: 3904
14. [14]
  [14] Collier A, Wang H J, Yuan X Z, Zhang J J, Wilkinson D P. Int J Hydrogen Energy, 2006, 31: 1838
15. [15]
  [15] Inaba M, Kinumoto T, Kiriake M, Umebayashi R, Tasaka A, Ogumi Z. Electrochim Acta, 2006, 51: 5746
16. [16]
  [16] Jablonski A, Lewera A. Appl Catal B, 2012, 115-116: 25
17. [17]
  [17] Jablonski A, Kulesza P J, Lewera A. J Power Sources, 2011, 196: 4714
18. [18]
  [18] Seweryn J, Lewera A. Appl Catal B, 2014, 144: 129
19. [19]
  [19] Seweryn J, Lewera A. J Power Sources, 2012, 205: 264
20. [20]
  [20] Vigier F, Coutanceau C, Hahn F, Belgsir E M, Lamy C. J Electroanal Chem, 2004, 563: 81
21. [21]
  [21] Wang J T, Wasmus S, Savinell R F. J Electrochem Soc, 1995, 142: 4218
22. [22]
  [22] Rousseau S, Coutanceau C, Lamy C, Leger J M. J Power Sources, 2006, 158: 18
23. [23]
  [23] Jin J M, Sheng T, Lin X, Kavanagh R, Hamer P, Hu P J, Hardacre C, Martinez-Bonastre A, Sharman J, Thompsett D, Lin W F. Phys Chem Chem Phys, 2014, 16: 9432
24. [24]
  [24] Januszewska A, Dercz G, Piwowar J, Jurczakowski R, Lewera A. Chem Eur J, 2013, 19: 17159
25. [25]
  [25] Kolary-Zurowska A, Zieleniak A, Miecznikowski K, Baranowska B, Lewera A, Fiechter S, Bogdanoff P, Dorbandt I, Marassi R, Kulesza P J. J Solid State Electrochem, 2007, 11: 915
26. [26]
  [26] Li M, Kowal A, Sasaki K, Marinkovic N, Su D, Korach E, Liu P, Adzic R R. Electrochim Acta, 2010, 55: 4331
27. [27]
  [27] Kowal A, Li M, Shao M, Sasaki K, Vukmirovic M B, Zhang J, Marinkovic N S, Liu P, Frenkel A I, Adzic R R. Nat Mater, 2009, 8: 325
28. [28]
  [28] Figueiredo M C, Aran-Ais R M, Feliu J M, Kontturi K, Kallio T. J Catal, 2014, 312: 78
29. [29]
  [29] Choban E R, Markoski L J, Wieckowski A, Kenis P J A. J Power Sources, 2004, 128: 54
30. [30]
  [30] Jayashree R S, Gancs L, Choban E R, Primak A, Natarajan D, Markoski L J, Kenis P J A. J Am Chem Soc, 2005, 127: 16758
31. [31]
  [31] Hitmi H, Belgsir E M, Leger J M, Lamy C, Lezna R O. Electrochim Acta, 1994, 39: 407
32. [32]
  [32] Watanabe M, Motoo S. J Electroanal Chem Interfacial Electrochem, 1975, 60: 267
33. [33]
  [33] Watanabe M, Motoo S. J Electroanal Chem Interfacial Electrochem, 1975, 60: 275
34. [34]
  [34] Kutz R B, Braunschweig B, Mukherjee P, Behrens R L, Dlott D D, Wieckowski A. J Catal, 2011, 278: 181
35. [35]
  [35] Heinen M, Jusys Z, Behm R J. J Phys Chem C, 2010, 114: 9850
1. [1]
  Chunru Liu , Ligang Feng . Advances in anode catalysts of methanol-assisted water-splitting reactions for hydrogen generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100136-100136. doi: 10.1016/j.cjsc.2023.100136
2. [2]
  Guan-Nan Xing , Di-Ye Wei , Hua Zhang , Zhong-Qun Tian , Jian-Feng Li . Pd-based nanocatalysts for oxygen reduction reaction: Preparation, performance, and in-situ characterization. Chinese Journal of Structural Chemistry, 2023, 42(11): 100021-100021. doi: 10.1016/j.cjsc.2023.100021
3. [3]
  Shaojie Ding , Henan Wang , Xiaojing Dai , Yuru Lv , Xinxin Niu , Ruilian Yin , Fangfang Wu , Wenhui Shi , Wenxian Liu , Xiehong Cao . Mn-modulated Co–N–C oxygen electrocatalysts for robust and temperature-adaptative zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100302-100302. doi: 10.1016/j.cjsc.2024.100302
4. [4]
  Pingfan Zhang , Shihuan Hong , Ning Song , Zhonghui Han , Fei Ge , Gang Dai , Hongjun Dong , Chunmei Li . Alloy as advanced catalysts for electrocatalysis: From materials design to applications. Chinese Chemical Letters, 2024, 35(6): 109073-. doi: 10.1016/j.cclet.2023.109073
5. [5]
  Jin Long , Xingqun Zheng , Bin Wang , Chenzhong Wu , Qingmei Wang , Lishan Peng . Improving the electrocatalytic performances of Pt-based catalysts for oxygen reduction reaction via strong interactions with single-CoN₄-rich carbon support. Chinese Chemical Letters, 2024, 35(5): 109354-. doi: 10.1016/j.cclet.2023.109354
6. [6]
  Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt₃M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188
7. [7]
  Jialin Cai , Yizhe Chen , Ruiwen Zhang , Cheng Yuan , Zeyu Jin , Yongting Chen , Shiming Zhang , Jiujun Zhang . Interfacial Pt-N coordination for promoting oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(2): 110255-. doi: 10.1016/j.cclet.2024.110255
8. [8]
  Hongliang Zeng , Yuan Ji , Jinfeng Wen , Xu Li , Tingting Zheng , Qiu Jiang , Chuan Xia . Pt nanocluster-catalyzed hydrogen evolution reaction: Recent advances and future outlook. Chinese Chemical Letters, 2025, 36(3): 109686-. doi: 10.1016/j.cclet.2024.109686
9. [9]
  Shengkai Li , Yuqin Zou , Chen Chen , Shuangyin Wang , Zhao-Qing Liu . Defect engineered electrocatalysts for C–N coupling reactions toward urea synthesis. Chinese Chemical Letters, 2024, 35(8): 109147-. doi: 10.1016/j.cclet.2023.109147
10. [10]
  Yue Zhang , Xiaoya Fan , Xun He , Tingyu Yan , Yongchao Yao , Dongdong Zheng , Jingxiang Zhao , Qinghai Cai , Qian Liu , Luming Li , Wei Chu , Shengjun Sun , Xuping Sun . Ambient electrosynthesis of urea from carbon dioxide and nitrate over Mo₂C nanosheet. Chinese Chemical Letters, 2024, 35(8): 109806-. doi: 10.1016/j.cclet.2024.109806
11. [11]
  Xianxu Chu , Lu Wang , Junru Li , Hui Xu . Surface chemical microenvironment engineering of catalysts by organic molecules for boosting electrocatalytic reaction. Chinese Chemical Letters, 2024, 35(8): 109105-. doi: 10.1016/j.cclet.2023.109105
12. [12]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
13. [13]
  Wei Zhou , Xi Chen , Lin Lu , Xian-Rong Song , Mu-Jia Luo , Qiang Xiao . Recent advances in electrocatalytic generation of indole-derived radical cations and their applications in organic synthesis. Chinese Chemical Letters, 2024, 35(4): 108902-. doi: 10.1016/j.cclet.2023.108902
14. [14]
  Zhihao Gu , Jiabo Le , Hehe Wei , Zehui Sun , Mahmoud Elsayed Hafez , Wei Ma . Unveiling the intrinsic properties of single NiZnFeO_x entity for promoting electrocatalytic oxygen evolution. Chinese Chemical Letters, 2024, 35(4): 108849-. doi: 10.1016/j.cclet.2023.108849
15. [15]
  Zhao Li , Huimin Yang , Wenjing Cheng , Lin Tian . Recent progress of in situ/operando characterization techniques for electrocatalytic energy conversion reaction. Chinese Chemical Letters, 2024, 35(9): 109237-. doi: 10.1016/j.cclet.2023.109237
16. [16]
  Weiping Xiao , Yuhang Chen , Qin Zhao , Danil Bukhvalov , Caiqin Wang , Xiaofei Yang . Constructing the synergistic active sites of nickel bicarbonate supported Pt hierarchical nanostructure for efficient hydrogen evolution reaction. Chinese Chemical Letters, 2024, 35(12): 110176-. doi: 10.1016/j.cclet.2024.110176
17. [17]
  Ting Xie , Xun He , Lang He , Kai Dong , Yongchao Yao , Zhengwei Cai , Xuwei Liu , Xiaoya Fan , Tengyue Li , Dongdong Zheng , Shengjun Sun , Luming Li , Wei Chu , Asmaa Farouk , Mohamed S. Hamdy , Chenggang Xu , Qingquan Kong , Xuping Sun . CoSe₂ nanowire array enabled highly efficient electrocatalytic reduction of nitrate for ammonia synthesis. Chinese Chemical Letters, 2024, 35(11): 110005-. doi: 10.1016/j.cclet.2024.110005
18. [18]
  Quanyou Guo , Yue Yang , Tingting Hu , Hongqi Chu , Lijun Liao , Xuepeng Wang , Zhenzi Li , Liping Guo , Wei Zhou . Regulating local electron transfer environment of covalent triazine frameworks through F, N co-modification towards optimized oxygen reduction reaction. Chinese Chemical Letters, 2025, 36(1): 110235-. doi: 10.1016/j.cclet.2024.110235
19. [19]
  Bowen Li , Ting Wang , Ming Xu , Yuqi Wang , Zhaoxing Li , Mei Liu , Wenjing Zhang , Ming Feng . Structuring MoO₃-polyoxometalate hybrid superstructures to boost electrocatalytic hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(2): 110467-. doi: 10.1016/j.cclet.2024.110467
20. [20]
  Hong-Rui Li , Xia Kang , Rui Gao , Miao-Miao Shi , Bo Bi , Ze-Yu Chen , Jun-Min Yan . Interfacial interactions of Cu/MnOOH enhance ammonia synthesis from electrochemical nitrate reduction. Chinese Chemical Letters, 2025, 36(2): 109958-. doi: 10.1016/j.cclet.2024.109958

Get Citation

PDF

XML

Metrics

PDF Downloads(254)
Abstract views(469)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142