Citation: Hao Liang, Zhihui Ren, Yaoyu Wang, Zhenghui Guan. One-pot green synthesis of enamides and 1,3-diynes[J]. Chinese Journal of Catalysis, ;2015, 36(1): 113-118. doi: 10.1016/S1872-2067(14)60220-5 shu

One-pot green synthesis of enamides and 1,3-diynes

1.
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi'an 710127, Shaanxi, China

Corresponding author: Zhenghui Guan,
Received Date: 19 July 2014
Available Online: 2 September 2014
Fund Project: 国家自然科学基金(21272183) (21272183) 陕西省科技厅“陕西省青年科技新星”基金(2012KJXX-26). (2012KJXX-26)

A green organic synthetic method combining reductive acylation of ketoximes and oxidative coupling of terminal alkynes was developed. This novel process enables enamides and 1,3-diynes to be synthesized simultaneously in high yields and under mild conditions without the use of terminal reductants/oxidants.
- Green synthesis,
- Ketoxime,
- Terminal alkyne,
- Enamide,
- 1,3-Diyne
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