Citation: Zhe Li, Lei Liu. Recent advances in mechanistic studies on Ni catalyzed cross-coupling reactions[J]. Chinese Journal of Catalysis, ;2015, 36(1): 3-14. doi: 10.1016/S1872-2067(14)60217-5 shu

Recent advances in mechanistic studies on Ni catalyzed cross-coupling reactions

Zhe Li ,
Lei Liu ^,

1.
Department of Chemistry, Tsinghua University, Beijing 100084, China

Corresponding author: Lei Liu,
Received Date: 11 August 2014
Available Online: 4 September 2014
Fund Project: 国家高技术研究发展计划(863计划, 2012AA02A700) (863计划, 2012AA02A700) 国家自然科学基金(21221062). (21221062)

A variety of Ni catalyzed cross-coupling reactions have emerged as efficient new methods for the construction of C-C bonds, and many mechanistic studies have been conducted to understand the factors controlling the reactivity and selectivity of Ni catalyzed reactions. The mechanisms of Ni catalyzed reactions are often very different from the corresponding Pd catalyzed processes because radical or bimetallic pathways are frequently involved in Ni catalyzed cross-coupling reactions. This review summarized recent advances in the mechanism of Ni catalyzed cross-coupling reactions. These are important for the development of new Ni catalyzed cross-coupling reactions with improved efficiency and selectivity.
- Nickel,
- Homogeneous catalysis,
- Cross-coupling,
- C-C bond formation,
- Mechanism
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