Citation: Zhijun Chen, Yanhua Wang, Wenjiang Li, Jingyang Jiang, Zilin Jin. Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene[J]. Chinese Journal of Catalysis, ;2014, 35(12): 1917-1920. doi: 10.1016/S1872-2067(14)60216-3 shu

Thermoregulated phase-transfer Rh nanoparticle catalyst for selective hydrogenation of ortho-chloronitrobenzene

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, Liaoning, China

Corresponding author: Yanhua Wang,
Received Date: 26 July 2014
Available Online: 29 August 2014
Fund Project: 国家自然科学基金(21173031) (21173031) 中央高校基本科研业务费专项资金(DUT13ZD206) (DUT13ZD206)

The use of athermoregulated phase-transfer Rh nanoparticle catalyst for the selective hydrogenation of ortho-chloronitrobenzene (o-CNB) to ortho-chloroaniline (o-CAN) in an aqueous/1-pentanol biphasic system was studied. Under the optimized reaction conditions, the conversion of o-CNB and the selectivity for o-CAN were 100% and 98%, respectively. The catalyst was easily separated from the product by phase separation and reused eight times without evident loss of activity and selectivity.
- Thermoregulated ligand,
- Rhodium nanoparticle,
- Ortho-chloronitrobenzene,
- Selective hydrogenation,
- Aqueous/1-pentanol biphasic system
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沈阳化工大学材料科学与工程学院沈阳 110142