Citation: Tianliang Lu, Zhongtian Du, Junxia Liu, Chen Chen, Jie Xu. Dehydrogenation of primary aliphatic alcohols to aldehydes over Cu-Ni bimetallic catalysts[J]. Chinese Journal of Catalysis, ;2014, 35(12): 1911-1916. doi: 10.1016/S1872-2067(14)60208-4 shu

Dehydrogenation of primary aliphatic alcohols to aldehydes over Cu-Ni bimetallic catalysts

Tianliang Lu ^a,b ,
Zhongtian Du ^a ,
Junxia Liu ^a,b ,
Chen Chen ^a ,
Jie Xu ^a,,

1.
a. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Jie Xu,
Received Date: 27 June 2014
Available Online: 15 August 2014
Fund Project: 国家自然科学基金(21203180和21233008). (21203180和21233008)

The catalytic conversion of non-activated primary aliphatic alcohols to aldehydes is a challenge, and monometallic Cu-based catalysts loaded on different supports have often been used for these reactions. Cu-Ni/γ-Al₂O₃ bimetallic catalysts were prepared and used for anaerobic dehydrogenation of 3,3-dimethyl-1-butanol to 3,3-dimethyl-1-butanal. These catalysts exhibited higher activity than Cu/γ-Al₂O₃ under the same reaction conditions, and a wide range of primary aliphatic alcohols were efficiently converted to the corresponding aldehydes over Cu-Ni/γ-Al₂O₃ under mild conditions.
- Primary aliphatic alcohol,
- Aldehyde,
- Copper-nickel,
- Catalysis,
- Dehydrogenation
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