Citation: Qinsheng Zhang, Haifeng Li, Ping Gao, Lailai Wang. PVP-NiB amorphous catalyst for selective hydrogenation of phenol and its derivatives[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1793-1799. doi: 10.1016/S1872-2067(14)60203-5 shu

PVP-NiB amorphous catalyst for selective hydrogenation of phenol and its derivatives

1.
a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China;

Corresponding author: Ping Gao, Lailai Wang,
Received Date: 25 June 2014
Available Online: 24 July 2014
Fund Project: 国家自然科学基金(21174115) (21174115)甘肃省青年基金(1308RJYA036). (1308RJYA036)

PVP-NiB amorphous catalysts were prepared by the chemical reduction of nickel chloride with sodium borohydride, and characterized by infrared, X-ray diffraction, transmission election microscopy, and inductively coupled plasma. The relationship between the catalytic activity and nature of the active sites was discussed. PVP is a protective agent for preparing PVP-stabilized NiB catalysts, which improved the dispersion of the catalyst and stabilized its amorphous structure. The catalysis of phenol and its derivatives was evaluated in the aqueous phase. 99.9% conversion of phenol and 99.9% selectivity to cyclohexanol were obtained at 30 ℃ and 0.2 MPa H₂ after 18 h over PVP-NiB. The generality of the PVP-NiB catalyst for this reaction was demonstrated by the selective hydrogenation of other phenol derivatives, which showed that the PVP-NiB catalyst was selective for the formation of cyclohexanol.
- Nickel,
- Phenol,
- Catalytic hydrogenation,
- Amorphous catalyst
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沈阳化工大学材料科学与工程学院沈阳 110142