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Citation: Runqin Wang, Ronghe Lin, Yunjie Ding, Jia Liu, Wenting Luo, Hong Du, Yuan Lü. Highly hydrothermally stable FePO4-SBA-15 synthesized using a novel one-pot hydrothermal method[J]. Chinese Journal of Catalysis, ;2015, 36(3): 446-453. doi: 10.1016/S1872-2067(14)60202-3 shu

Highly hydrothermally stable FePO4-SBA-15 synthesized using a novel one-pot hydrothermal method

  • 1.

    a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

  • Corresponding author: Yunjie Ding, 
  • Received Date: 9 October 2014
    Available Online: 18 November 2014

    Fund Project: 国家自然科学基金(21103170). (21103170)

  • The hydrothermal stability of FePO4-SBA-15 synthesized using a novel one-pot hydrothermal method (OP) was systematically investigated using two methods: treatment with pure steam at 800 ℃ or with boiling water at 100 ℃. The structural changes in the samples were monitored using small angle X-ray diffraction and N2-physisorption methods. It was found that the hydrothermal stabilities of OP samples remained high and showed little difference over the FePO4-doping range 5-40 wt%. These results differ from previous reports that the loading of heterogeneous metal atoms significantly influences the hydrothermal stability of the host ordered mesoporous material. For comparison, the hydrothermal stabilities of FePO4-SBA-15 synthesized using an impregnation method (IMP) and commercially obtained SBA-15 were also studied. The order of the sample hydrothermal stabilities was OP > IMP >> SBA-15. The formed FePO4 protective layers helped to prevent mesostructure degradation during hydrothermal treatment, therefore modified samples showed superior hydrothermal stabilities compared with pure SBA-15. The superior performance of OP samples over IMP samples is mainly attributed to the formation of stable Si-O-Fe bonds and more micropores in OP samples.
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    1. [1]

      [1] Kresge C T, Leonowicz M E, Roth W J, Vartuli J C, Beck J S. Nature, 1992, 359: 710

    2. [2]

      [2] Beck J S, Vartuli J C, Roth W J, Leonowicz M E, Kresge C T, Schmitt K D, Chu C T W, Olson D H, Sheppard E W, Mccullen S B, Higgins J B, Schlenker J L. J Am Chem Soc, 1992, 114: 10834

    3. [3]

      [3] Taguchi A, Schüth F. Microporous Mesoporous Mater, 2005, 77: 1

    4. [4]

      [4] Corma A. Chem Rev, 1997, 97: 2373

    5. [5]

      [5] Perego C, Millini R. Chem Soc Rev, 2013, 42: 3956

    6. [6]

      [6] Da J W, Song C M, Qian L, Su J M, Xu X Z. J Porous Mater, 2008, 15: 189

    7. [7]

      [7] Eswaramoorthi I, Dalai A K. Int J Hydrogen Energy, 2009, 34: 2580

    8. [8]

      [8] Zhang F Q, Yan Y, Yang H F, Meng Y, Yu C Z, Tu B, Zhao D Y. J Phys Chem B, 2005, 109: 8723

    9. [9]

      [9] Mokaya R. Chem Commun, 2001: 633

    10. [10]

      [10] Liu H, Wang M Y, Hu H J, Liang Y G, Wang Y, Cao W R, Wang X H. J Solid State Chem, 2011, 184: 509

    11. [11]

      [11] Li Q, Wu Z X, Feng D, Tu B, Zhao D Y. J Phys Chem C, 2010, 114: 5012

    12. [12]

      [12] Shindo T, Nakazawa Y, Ozawa S. J Porous Mater, 2009, 16: 481

    13. [13]

      [13] Mody H M, Kannan S, Bajaj H C, Manu V, Jasra R V. J Porous Mater, 2008, 15: 571

    14. [14]

      [14] Liu Z Y, Zhu Z B, Wang R Y, Zhu X D. Chin J Catal(刘子玉, 朱子彬, 王仁远, 朱学栋. 催化学报), 2008, 29: 928

    15. [15]

      [15] Sangchoom W, Mokaya R. J Mater Chem, 2012, 22: 18872

    16. [16]

      [16] Ryoo R, Jun S. J Phys Chem B, 1997, 101: 317

    17. [17]

      [17] Jun S, Kim J M, Ryoo R, Ahn Y S, Han M H. Microporous Mesoporous Mater, 2000, 41: 119

    18. [18]

      [18] Kim J M, Jun S, Ryoo R. J Phys Chem B, 1999, 103: 6200

    19. [19]

      [19] Song M J, Zou C L, Niu G X, Zhao D Y. Chin J Catal(宋明娟, 邹成龙, 牛国兴, 赵东元. 催化学报), 2012, 33: 140

    20. [20]

      [20] Li Q, Wu Z X, Tu B, Park S S, Ha C S, Zhao D Y. Microporous Mesoporous Mater, 2010, 135: 95

    21. [21]

      [21] Selvaraj M, Kawi S, Park D W, Ha C S. Microporous Mesoporous Mater, 2009, 117: 586

    22. [22]

      [22] Selvaraj M, Kawi S, Park D W, Ha C S. J Phys Chem C, 2009, 113: 7743

    23. [23]

      [23] Mokaya R. J Phys Chem B, 2000, 104: 8279

    24. [24]

      [24] Selvaraj M, Kawi S. Chem Mater, 2007, 19: 509

    25. [25]

      [25] Wang R Q, Lin R H, Ding Y J, Liu J, Wang J H, Zhang T. Appl Catal A, 2013, 453: 235

    26. [26]

      [26] Lin R H, Ding Y J, Gong L F, Dong W D, Chen W M, Lu Y. Catal Today, 2011, 164: 34

    27. [27]

      [27] Selvaraj M, Park D W, Ha C S. Microporous Mesoporous Mater, 2011, 138: 94

    28. [28]

      [28] Groen J C, Perez-Ramirez J. Appl Catal A, 2004, 268: 121

    29. [29]

      [29] Shen S C, Kawi S. J Phys Chem B, 1999, 103: 8870

    30. [30]

      [30] Shao Y F, Wang L Z, Zhang J L, Anpo M. Microporous Mesoporous Mater, 2008, 109: 271

    31. [31]

      [31] Sano T, Nakajima Y, Wang Z B, Kawakami Y, Soga K, Iwasaki A. Microporous Mater, 1997, 12: 71

    32. [32]

      [32] Wang K X, Lin Y J, Morris M A, Holmes J D. J Mater Chem, 2006, 16: 4051

    33. [33]

      [33] Wang Y, Wang X X, Su Z, Guo Q, Tang Q H, Zhang Q H, Wan H L. Catal Today, 2004, 93-95: 155

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