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Citation: Xingquan Xiong, Huixin Chen, Rongjun Zhu. Oyster shell waste supported CuCl2 for aldehyde-alkyne-amine coupling reaction to propargylamines[J]. Chinese Journal of Catalysis, ;2014, 35(12): 2006-2013. doi: 10.1016/S1872-2067(14)60195-9 shu

Oyster shell waste supported CuCl2 for aldehyde-alkyne-amine coupling reaction to propargylamines

  • 1.

    College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, Fujian, China

  • Corresponding author: Xingquan Xiong, 
  • Received Date: 8 June 2014
    Available Online: 17 July 2014

    Fund Project: 国家自然科学基金(21004024) (21004024) 福建省自然科学基金(2011J01046) (2011J01046) 福建省“高校新世纪优秀人才支持计划”(2012FJ-NCET-ZR03) (2012FJ-NCET-ZR03) 福建省“高校杰出青年科研人才培育计划”(11FJPY02) (11FJPY02) “华侨大学中青年教师科研提升资助计划” (ZQN-YX103). (ZQN-YX103)

  • The development of an economic and simple heterogeneous oyster shell waste supported CuCl2 catalyst for the aldehyde-alkyne-amine (A3) coupling reaction was reported. The waste oyster shell powder (OSP) supported CuCl2 (OSP-CuCl2) catalyst was prepared by a simple method from waste OSPs and CuCl2, which was shown to be a highly active and recyclable catalyst for the A3-coupling reaction. A range of propargylamines were obtained in good to excellent yields (85%-97%) under solvent-free and microwave-heated conditions. The OSP-CuCl2 catalyst can be simply recovered by filtration and reused for at least six runs. Propargylamine can be produced in 87% yield even when the scale of the A3-coupling reaction was increased to 150 mmol.
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