Citation: Nanfang Tang, Xiaoping Zhao, Zongxuan Jiang, Can Li. Oxidation of dibenzothiophene using oxygen and a vanadophosphate catalyst for ultra-deep desulfurization of diesels[J]. Chinese Journal of Catalysis, ;2014, 35(9): 1433-1437. doi: 10.1016/S1872-2067(14)60194-7 shu

Oxidation of dibenzothiophene using oxygen and a vanadophosphate catalyst for ultra-deep desulfurization of diesels

Nanfang Tang ^a,b ,
Xiaoping Zhao ^c ,
Zongxuan Jiang ^a,, ,
Can Li ^a,,

1.
a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Zongxuan Jiang, Can Li,
Received Date: 30 May 2014
Available Online: 18 July 2014
Fund Project:

A bicapped Keggin structure vanadophosphate showed high catalytic activity in the oxidation of dibenzothiophene (DBT) to sulfone using molecular oxygen as oxidant under mild reaction conditions. This is a promising approach to the ultra-deep desulfurization of fuels (e.g. diesel) as sulfones can be removed from the fuel by extraction or selective adsorption.
- Oxidative desulfurization,
- Molecular oxygen,
- Vanadophosphate,
- Dibenzothiophene
1. [1]
  [1] Song C S. Catal Today, 2003, 86: 211
2. [2]
  [2] Chandra Srivastava V. RSC Adv, 2012, 2: 759
3. [3]
  [3] Jiang Z X, Lü H Y, Zhang Y N, Li C. Chin J Catal (蒋宗轩, 吕宏缨, 张永娜, 李灿. 催化学报), 2011, 32: 707
4. [4]
  [4] Chica A, Corma A, Domine M E. J Catal, 2006, 242: 299
5. [5]
  [5] Caero L C, Hernandez E, Pedraza F, Murrieta F. Catal Today, 2005, 107: 564
6. [6]
  [6] Ramirez-Verduzco L F, Torres-Garcia E, Gómez-Quintana R, Gonzalez-Penã V, Murrieta-Guevara F. Catal Today, 2004, 98: 289
7. [7]
  [7] Yazu K, Yamamoto Y, Furuya T, Miki K, Ukegawa K. Energy Fuels, 2001, 15: 1535
8. [8]
  [8] Zhang B Y, Jiang Z X, Li J, Zhang Y N, Lin F, Liu Y, Li C. J Catal, 2012, 287: 5
9. [9]
  [9] Li C, Jiang Z X, Gao J B, Yang Y X, Wang S J, Tian F P, Sun F X, Sun X P, Ying P L, Han C R. Chem-Eur J, 2004, 10: 2277
10. [10]
  [10] Zhang Y N, Wang L, Zhang Y L, Jiang Z X, Li C. Chin J Catal (张永娜,王璐, 张玉良, 蒋宗轩, 李灿. 催化学报), 2011, 32: 235
11. [11]
  [11] Tam P S, Kittrell J R, Eldridge J W. Ind Eng Chem Res, 1990, 29: 321
12. [12]
  [12] Yang L W, Li J, Yuan X D, Shen J, Qi Y T. J Mol Catal A, 2007, 262: 114
13. [13]
  [13] Babich I V, Moulijn J A. Fuel, 2003, 82: 607
14. [14]
  [14] Tang N F, Zhang Y N, Lin F, Lü H Y, Jiang Z X, Li C. Chem Commun, 2012, 48: 11647
15. [15]
  [15] Lü H Y, Zhang Y N, Jiang Z X, Li C. Green Chem, 2010, 12: 1954
16. [16]
  [16] Rocchiccioli-Deltcheff C, Fournier M, Franck R, Thouvenot R. Inorg Chem, 1983, 22: 207
17. [17]
  [17] Edwards J C, Thiel C Y, Benac B, Knifton J F. Catal Lett, 1998, 51: 77
18. [18]
  [18] Selling A, Andersson I, Pettersson L, Schramm C M, Downey S L, Grate J H. Inorg Chem, 1994, 33: 3141
19. [19]
  [19] Kato R, Kobayashi A, Sasaki Y. Inorg Chem, 1982, 21: 240
20. [20]
  [20] Ogunlaja A S, Chidawanyika W, Antunes E, Fernandes M A, Nyokong T, Torto N, Tshentu Z R. Dalton Trans, 2012, 41: 13908
21. [21]
  [21] Leonard S, Gannett P M, Rojanasakul Y, Schwegler-Berry D, Castranova V, Vallyathan V, Shi X L. J Inorg Biochem, 1998, 70: 239
22. [22]
  [22] Lin F, Wang D G, Jiang Z X, Ma Y, Li J, Li R G, Li C. Energy Environ Sci, 2012, 5: 6400
1. [1]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
2. [2]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
3. [3]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 2309027-0. doi: 10.3866/PKU.WHXB202309027
4. [4]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
5. [5]
  Hailang JIA , Pengcheng JI , Hongcheng LI . Preparation and performance of nickel doped ruthenium dioxide electrocatalyst for oxygen evolution. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1632-1640. doi: 10.11862/CJIC.20240398
6. [6]
  Yinjie Xu , Suiqin Li , Lihao Liu , Jiahui He , Kai Li , Mengxin Wang , Shuying Zhao , Chun Li , Zhengbin Zhang , Xing Zhong , Jianguo Wang . Enhanced Electrocatalytic Oxidation of Sterols using the Synergistic Effect of NiFe-MOF and Aminoxyl Radicals. Acta Physico-Chimica Sinica, 2024, 40(3): 2305012-0. doi: 10.3866/PKU.WHXB202305012
7. [7]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023
8. [8]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
9. [9]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
10. [10]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
11. [11]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
12. [12]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
13. [13]
  Wang Wang , Yucheng Liu , Shengli Chen . Use of NiFe Layered Double Hydroxide as Electrocatalyst in Oxygen Evolution Reaction: Catalytic Mechanisms, Electrode Design, and Durability. Acta Physico-Chimica Sinica, 2024, 40(2): 2303059-0. doi: 10.3866/PKU.WHXB202303059
14. [14]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
15. [15]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
16. [16]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
17. [17]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
18. [18]
  Wenhui Li , Yakun Tang , Yusheng Zhou , Yue Zhang , Wenhai Zhang , Qingtao Ma , Lang Liu , Sen Dong , Yuliang Cao . Enhanced sodium storage performance of asphalt-derived hard carbon through intramolecular oxidation for high-performance sodium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(10): 100119-0. doi: 10.1016/j.actphy.2025.100119
19. [19]
  Huafeng SHI . Construction of MnCoNi layered double hydroxide@Co-Ni-S amorphous hollow polyhedron composite with excellent electrocatalytic oxygen evolution performance. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1380-1386. doi: 10.11862/CJIC.20240378
20. [20]
  Yinuo Wang , Ziyu Liu , Hongxia Tan , Jun Tong , Dazhen Xu . Synthesis of Bromobenzoxazine: Introduce a Comprehensive Organic Chemistry Experiment Transformed from Undergraduate Research Innovation. University Chemistry, 2025, 40(10): 208-216. doi: 10.12461/PKU.DXHX202411077

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(606)
HTML views(34)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142