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Citation: Zheng-Le Zhao, Qing Gu, Xin-Yan Wu, Shu-Li You. Pd(0)-catalyzed benzylation of indole through η3-benzyl palladium intermediate[J]. Chinese Journal of Catalysis, ;2015, 36(1): 15-18. doi: 10.1016/S1872-2067(14)60191-1 shu

Pd(0)-catalyzed benzylation of indole through η3-benzyl palladium intermediate

  • 1.

    a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, China;

  • Corresponding author: Shu-Li You, 
  • Received Date: 13 June 2014
    Available Online: 3 July 2014

    Fund Project: 国家重点基础研究发展计划(973计划, 2010CB833300) (973计划, 2010CB833300) 国家自然科学基金(21025209, 21121062, 21272253, 21332009). (21025209, 21121062, 21272253, 21332009)

  • An efficient method has been developed for the Pd(0)-catalyzed benzylation of indoles, which occurred with exclusive regioselectivity. When this reaction was performed in the presence of Pd(PPh3)4, it provided access to a broad range of substituted indoles bearing diarylmethanes at their 3-position in 90%-99% yields under mild conditions.
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