Citation: Hong Jiang, Xiaoxu Sun, Yan Du, Rizhi Chen, Weihong Xing. Catalytic activity of palladium nanoparticles immobilized on an amino-functionalized ceramic membrane support[J]. Chinese Journal of Catalysis, ;2014, 35(12): 1990-1996. doi: 10.1016/S1872-2067(14)60190-X shu

Catalytic activity of palladium nanoparticles immobilized on an amino-functionalized ceramic membrane support

Hong Jiang ^a ,
Xiaoxu Sun ^a ,
Yan Du ^b ,
Rizhi Chen ^a,, ,
Weihong Xing ^a,,

1.
a. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, Jiangsu, China;

Corresponding author: Rizhi Chen, Weihong Xing,
Received Date: 22 May 2014
Available Online: 3 July 2014
Fund Project: 国家自然科学基金(21106061, 21125629) (21106061, 21125629) 江苏省自然科学基金(BK20130920). (BK20130920)

Pd nanoparticles were immobilized on a tubular ceramic membrane support. The support surface was functionalized by N-(β-aminoethyl)-γ-aminopropyl trimethoxy silane (AAPTS), which contains two amino groups. The Pd-immobilized ceramic membrane support was characterized by X-ray diffraction, field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, inductively coupled plasma emission spectroscopy, X-ray photoelectron spectroscopy, and high-resolution transmission electron microscopy. Its catalytic properties were investigated by the liquid phase hydrogenation of p-nitrophenol to p-aminophenol. The Pd-immobilized ceramic membrane support was compared with the Pd nanoparticles immobilized on a similar support functionalized by γ-amino-propyltriethoxy silane (3-APTS), which contains one amino group. Higher catalytic activity and stability were observed for the AAPTS-functionalized support. AAPTS contains twice as many amino groups as 3-APTS, and consequently exhibited a stronger electron-donating effect toward Pd. The AAPTS-functionalized ceramic membrane support contained more immobilized Pd nanoparticles, which were bound more strongly. This led to a higher catalytic activity and stability.
- Palladium nanoparticle,
- N-(β-aminoethyl)-γ-aminopropyl,
- trimethoxy silane,
- Ceramic membrane
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