Citation: Jiashun Cheng, Pinhong Chen, Guosheng Liu. Pd-catalyzed intramolecular aminofluorination of allylic sulfamides[J]. Chinese Journal of Catalysis, ;2015, 36(1): 40-47. doi: 10.1016/S1872-2067(14)60164-9 shu

Pd-catalyzed intramolecular aminofluorination of allylic sulfamides

1.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Corresponding author: Guosheng Liu,
Received Date: 19 May 2014
Available Online: 9 June 2014
Fund Project: 国家重点基础研究发展计划(973计划, 2011CB808700) (973计划, 2011CB808700) 国家自然科学基金(21225210, 20923005和21121062) (21225210, 20923005和21121062) 上海市科学技术委员会(11JC1415000) (11JC1415000)

A facile Pd-catalyzed intramolecular aminofluorination reaction of allylic sulfamides was developed that can be used to prepare fluorinated 1,3-diamine derivatives. Acetic acid was essential for regulation to give the major 6-endo cyclization products.
- Palladium-catalyzed,
- Aminofluorination,
- Alkene,
- Fluorinated 1,3-diamine,
- 6-Endo cyclization
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