Citation: Zhaoyan Zhang, Ying Wang, Xian Li, Wei-Lin Dai. Synergistic effect on Au-Pd bimetallic catalyst during oxidation of benzyl alcohol to sodium benzoate[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1846-1857. doi: 10.1016/S1872-2067(14)60159-5 shu

Synergistic effect on Au-Pd bimetallic catalyst during oxidation of benzyl alcohol to sodium benzoate

1.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China

Corresponding author: Wei-Lin Dai,
Received Date: 6 May 2014
Available Online: 26 May 2014
Fund Project: 国家重点基础研究发展计划(973计划,2012CB224804) (973计划,2012CB224804) 国家自然科学基金(21373054,21173052) (21373054,21173052) 上海市科学技术委员会上海市自然科学基金(08DZ2270500). (08DZ2270500)

A series of AuPd/CeO₂ bimetallic catalysts with different Au/Pd molar ratios were investigated and their catalytic performance in the oxidation of benzyl alcohol to sodium benzoate and benzoic acid under solvent-free conditions was studied. The supported catalysts were characterized by X-ray diffraction, UV-Vis diffuse reflectance spectroscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The Au-Pd nanoparticles were successfully deposited onto CeO₂ as a homogeneous alloy. The activity of the bimetallic catalysts was superior to that of the corresponding monometallic catalysts. This improvement was attributed to the synergistic effect between Au and Pd. The catalyst with an Au/Pd molar ratio of 3/1 showed the best catalytic performance (the yield of benzoic acid reached 92%), and it could be easily recovered and reused for more than seven successive reactions without significant loss of activity.
- Gold,
- Palladium,
- Ceria,
- Bimetallic catalyst,
- Benzyl alcohol,
- Catalytic oxidation,
- Benzoate
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