Citation: Junying Zhang, Xiaofeng Yang, Baolin Hou, Aiqin Wang, Zhenlei Li, Hua Wang, Tao Zhang. Comparison of cellobiose and glucose transformation to ethylene glycol[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1811-1817. doi: 10.1016/S1872-2067(14)60151-0 shu

Comparison of cellobiose and glucose transformation to ethylene glycol

Junying Zhang ^a,b ,
Xiaofeng Yang ^a ,
Baolin Hou ^a ,
Aiqin Wang ^a,, ,
Zhenlei Li ^a,b ,
Hua Wang ^a ,
Tao Zhang ^a,,

1.
a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Aiqin Wang, Tao Zhang,
Received Date: 29 April 2014
Available Online: 10 May 2014
Fund Project: 国家自然科学基金(21176235,21373206,21206159). (21176235,21373206,21206159)

Cellobiose was used as a model feedstock to probe the reaction pathways of cellulose to ethylene glycol (EG). Its reactivity was compared with that of glucose using a catalyst composed of H₂WO₄ and Ru/C. EG can be produced by both the direct retro-aldol condensation of cellobiose and the retro-aldol condensation of glucose derived from cellobiose hydrolysis. The direct retro-aldol condensation of cellobiose further promoted the hydrolysis of cellobiose. Cellobiose has a lower reactivity for retro-aldol condensation than glucose, which decreased the formation rate of glycolaldehyde and made it more matched with the subsequent hydrogenation rate, thus leading to increased yield of EG from cellobiose.
- Cellobiose,
- Reaction mechanism,
- Glucose,
- Ethylene glycol
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