Citation: Pei Tang, Yongjun Gao, Jinghe Yang, Wenjing Li, Huabo Zhao, Ding Ma. Growth mechanism of N-doped graphene materials and their catalytic behavior in the selective oxidation of ethylbenzene[J]. Chinese Journal of Catalysis, ;2014, 35(6): 922-928. doi: 10.1016/S1872-2067(14)60150-9 shu

Growth mechanism of N-doped graphene materials and their catalytic behavior in the selective oxidation of ethylbenzene

1.
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: Ding Ma,
Received Date: 15 May 2014
Available Online: 21 May 2014
Fund Project: 国家自然科学基金(21176221，21273224)；国家重点基础研究发展计划(973计划，2011CB201402，2013CB933100). (21176221，21273224)；国家重点基础研究发展计划(973计划，2011CB201402，2013CB933100)

N-doped graphene materials were prepared from both inorganic and organic nitrogen sources and pyrolytic graphene oxide as the carbon substrate. Transmission electron microscopy, scanning electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy were used to investigate the detailed growth mechanism of the N species in these N-doped graphene materials. The different chemical nature and binding energy of the different N species resulted in their different trends with annealing temperature. These N-doped graphene are excellent catalysts in the oxidation of ethylbenzene. A high yield of acetonphenone did not depend on the total nitrogen amount but only on the type of nitrogen species. Too much defects and N-dopants were detrimental to this reaction. A proper activation of the oxidant is needed to get good catalytic activity.
- N-doped graphene,
- Heteroatom,
- Growth mechanism,
- Oxidation of ethylbenzene
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沈阳化工大学材料科学与工程学院沈阳 110142