Citation: Qiang Huang, Limei Zhou, Xiaohui Jiang, Xiaolong Qi, Zhonghua Wang, Wencheng Lang. Recyclable hydrophobic copper (Ⅱ) phthalocyanine catalyzed N-arylation of imidazoles in dimethylsulfoxide[J]. Chinese Journal of Catalysis, ;2014, 35(11): 1818-1824. doi: 10.1016/S1872-2067(14)60148-0 shu

Recyclable hydrophobic copper (Ⅱ) phthalocyanine catalyzed N-arylation of imidazoles in dimethylsulfoxide

1.
Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, China West Normal University, Nanchong 637002, Sichuan, China

Corresponding author: Limei Zhou,
Received Date: 11 April 2014
Available Online: 12 May 2014
Fund Project: 国家自然科学基金(21303139) (21303139)四川省教育厅项目(11ZA035) (11ZA035)四川省化学合成与污染控制重点实验室开放项目(CSPC2010-3). (CSPC2010-3)

Copper (Ⅱ) phthalocyanine (CuPc) was used as a catalyst for the N-arylation of imidazoles with aryl iodides or bromides. The catalyst showed high activity and could be reused 3 times without any significant loss in activity. The catalyst was characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and ultraviolet-visible spectroscopy.
- Copper (Ⅱ) phthalocyanine,
- N-arylation,
- Aryl halide,
- Recyclable catalyst
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沈阳化工大学材料科学与工程学院沈阳 110142