Citation: V. V. Strelko, S. S. Stavitskaya, Yu. I. Gorlov. Proton catalysis with active carbons and partially pyrolyzed carbonaceous materials[J]. Chinese Journal of Catalysis, ;2014, 35(6): 815-823. doi: 10.1016/S1872-2067(14)60147-9 shu

Proton catalysis with active carbons and partially pyrolyzed carbonaceous materials

1.
Institute for Sorption and Problems of Endoecology of NAS of Ukraine, 13 General Naumov St., 03164, Kyiv, Ukraine

Corresponding author: V. V. Strelko,
Received Date: 15 May 2014
Available Online: 19 May 2014

The development of environmentally friendly solid acid catalysts is a priority task. Highly oxidized activated carbon and their ion-substituted (saline) forms are effective proton transfer catalysts in esterification, hydrolysis, and dehydration, and thus are promising candidates as solid acid catalysts. Computations by the ab initio method indicated the cause for the enchanced acidity of the carboxylic groups attached to the surface of highly oxidized carbon. The synthesis of phosphorilated carbon was considered, and the proton transfer reactions catalyzed by them in recent studies were analyzed. The development of an amorphous carbon acid catalyst comprising polycyclic carbonaceous (graphene) sheets with-SO₃H,-COOH and phenolic type OH-groups was carried out. These new catalysts were synthesized by partial pyrolysis and subsequent sulfonation of carbohydrates, polymers, and other organic compounds. Their high catalytic activities in proton transfere reactions including the processing of bio-based raw materials was demonsrated.
- Active carbon,
- Oxidized carbon,
- Solid acid catalyst,
- Quantum chemical calculation,
- Sulfonated carbonaceous material,
- Phosphorylated carbon,
- Partially pyrolised organic compound,
- Catalytic conversion biobased raw,
- material
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1.
沈阳化工大学材料科学与工程学院沈阳 110142