Citation: Yingli Wang, Xin Chen, Zhengxi Yu, Lei Xu. Methanol aromatization over HZSM-5 catalysts modified with different zinc salts[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1740-1751. doi: 10.1016/S1872-2067(14)60145-5 shu

Methanol aromatization over HZSM-5 catalysts modified with different zinc salts

^a,b ,
Yingli Wang ^a ,
Xin Chen ^a ,
Zhengxi Yu ^a ,
Lei Xu ^a,,

1.
a Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, Chinab University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: Lei Xu,
Received Date: 22 March 2014
Available Online: 9 April 2014
Fund Project:

HZSM-5 catalysts modified with various Zn salts, namely zinc sulfate, zinc acetate, zinc nitrate, and zinc chloride, were prepared using an impregnation method. The resultant catalysts were characterized by X-ray diffraction, N₂ adsorption, thermogravimetry-mass spectrometry, temperature-programmed desorption of NH3, and infrared spectroscopy using pyridine as the probe molecule. The methanol-to-aromatic (MTA) performance over the modified catalysts was investigated. The results showed that the type of Zn species in the catalyst significantly influenced the catalyst surface acidity. The distribution of acid sites and Zn species in the HZSM-5 catalyst modified with zinc sulfate effectively improved the MTA performance.
- HZSM-5 zeolite,
- Zinc salt,
- Methanol,
- Aromatization
1. [1]
  [1] Zou H, Wu W, Si L, Zhu N, Shi J J. Acta Petrol Sin (Petrol Process Sect) (邹琥, 吴巍, 葸雷, 朱宁, 史军军. 石油学报(石油加工)), 2013, 29: 539
2. [2]
  [2] Keil F J. Microporous Mesoporous Mater, 1999, 29: 49
3. [3]
  [3] Stöcker M. Microporous Mesoporous Mater, 1999, 29: 3
4. [4]
  [4] Olsbye U, Svelle S, Bjorgen M, Beato P, Janssens T V W, Joensen F, Bordiga S, Lillerud K P. Angew Chem Int Ed, 2012, 51: 5810
5. [5]
  [5] Cejka J, Van Bekkum H. In: Di Renzo F, Fajula F O eds. Zeolites and Ordered Mesoporous Materials: Progress and Prospects. Amsterdam: Elsevier, 2005. 380
6. [6]
  [6] Chang C D, Silvestri A J. J Catal, 1977, 47: 249
7. [7]
  [7] Barthos R, Bansagi T, Zakar T S, Solymosi F. J Catal, 2007, 247: 368
8. [8]
  [8] Ono Y, Adachi H, Senoda Y. Chem Soc, Faraday Trans 1, 1988, 84: 1091
9. [9]
  [9] Jing H J, Yang F K, Xia Y M, Feng J Q, Liu J L, Zong Q Y. Petrol Sci Technol, 2012, 30: 1737
10. [10]
  [10] Ni Y M, Sun A M, Wu X L, Hai G L, Hu J L, Li T, Li G X. Microporous Mesoporous Mater, 2011, 143: 435
11. [11]
  [11] Zaidi H A, Pant K K. Catal Today, 2004, 96: 155
12. [12]
  [12] Xin Y B, Qi P Y, Duan X P, Lin H Q, Yuan Y Z. Catal Lett, 2013, 143: 798
13. [13]
  [13] Song C, Liu K F, Zhang D Z, Liu S L, Li X J, Xie S J, Xu L Y. Appl Catal A, 2014, 470: 15
14. [14]
  [14] Lopez-Sanchez J A, Conte M, Landon P, Zhou W, Bartley J K, Taylor S H, Carley A F, Kiely C J, Khalid K, Hutchings G J. Catal Lett, 2012, 142: 1049
15. [15]
  [15] Inoue Y, Nakashiro K, Ono Y. Microporous Mater, 1995, 4: 379
16. [16]
  [16] Conte M, Lopez-Sanchez J A, He Q, Morgan D J, Ryabenkova Y, Bartley J K, Carley A F, Taylor S H, Kiely C J, Khalid K, Hutchings G J. Catal Sci Technol, 2012, 2: 105
17. [17]
  [17] Ai Sha·N L H, Liu J X, He N, Guo H C. Chin J Catal (艾沙·努拉洪, 刘家旭, 贺宁, 郭洪臣. 催化学报), 2013, 34: 1262
18. [18]
  [18] She L Q, Wang D C, Li X W, Liu X Y, Han M. Acta Phys-Chim Sin (佘励勤, 王多才, 李宣文, 刘兴云, 韩明. 物理化学学报), 1993, 10: 247
19. [19]
  [19] Liu X Y, Li X W, She L Q, Yuan S B, Qin H Y. Acta Petrol Sin (Petrol Process Sec) (刘兴云, 李宣文, 佘励勤, 袁世斌, 秦皓昱. 石油学报(石油加工)), 1988, 4(4): 36
20. [20]
  [20] Komatsu T, Mesuda M, Yashima T. Appl Catal A, 2000, 194-195: 333
21. [21]
  [21] Song Y Q, Zhu X X, Xu L Y. Catal Commun, 2006, 7: 218
22. [22]
  [22] Tian T, Qian W Z, Tang X P, Hui S, Wei F. Acta Phys-Chim Sin (田涛, 骞伟中, 汤效平, 恽松, 魏飞. 物理化学学报), 2010, 26: 3305
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沈阳化工大学材料科学与工程学院沈阳 110142