Citation:
Lifeng Chen, Weilin Song, Yahong Zhang, Weimin Yang, Lianghua Wu, Yi Tang. Nanowire accumulated Fe2O3/SiO2 spherical catalyst for Fischer-Tropsch synthesis[J]. Chinese Journal of Catalysis,
;2014, 35(10): 1661-1668.
doi:
10.1016/S1872-2067(14)60135-2
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A catalyst consisting of SiO2 nanowires and highly dispersed Fe2O3 (denoted NW-FS) was synthesized in situ by iron-assisted amine-vapor-transport treatment. NW-FS was prepared by the direct transformation of an industrial spherical Fe2O3/SiO2 catalyst (denoted indus-FS). NW-FS was characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, N2-sorption measurements, X-ray photoelectron spectroscopy, and temperature-programmed reduction. NW-FS exhibited a high selectivity for light olefins, especially for ethene in the Fischer-Tropsch synthesis. This was because of the highly dispersed Fe2O3 and low diffusion resistance of its open structure. The C2-C4 olefin/paraffin ratio was 3.3, which was higher than that of indus-FS at 1.9.
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