Citation: Jiaying Cai, Hong Ma, Junjie Zhang, Zhongtian Du, Yizheng Huang, Jin Gao, Jie Xu. Catalytic oxidation of glycerol to tartronic acid over Au/HY catalyst under mild conditions[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1653-1660. doi: 10.1016/S1872-2067(14)60132-7 shu

Catalytic oxidation of glycerol to tartronic acid over Au/HY catalyst under mild conditions

Jiaying Cai ^a,b ,
Hong Ma ^a ,
Junjie Zhang ^a,b ,
Zhongtian Du ^a ,
Yizheng Huang ^a ,
Jin Gao ^a ,
Jie Xu ^a,,

1.
a Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;

Corresponding author: Jie Xu,
Received Date: 30 March 2014
Available Online: 28 April 2014
Fund Project:

Gold nanoclusters or nanoparticles on various supports (CeO₂, activated carbon, HY, REY, and NaY) were investigated for glycerol oxidation in the aqueous phase under mild conditions. Compared with other catalysts, Au/HY showed remarkable catalytic performance in forming dicarboxylic acid (tartronic acid) over the monocarboxylic acid (glyceric acid) or the C-C cleavage product (oxalic acid). Au/HY achieved 98% conversion of glycerol and 80% yield of tartronic acid at 60 ℃ under 0.3 MPa O₂. Further characterization showed that the small size of Au clusters is the key factor for the high oxidation performance. In situ Fourier transform infrared spectroscopy revealed that glycerol was first transformed to glyceric acid, and then glyceric acid was directly oxidized to tartronic acid.
- Catalytic oxidation,
- Glycerol,
- Gold,
- Tartronic acid
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沈阳化工大学材料科学与工程学院沈阳 110142