Citation: Yahui Sun, Zhenping Qu, Dan Chen, Hui Wang, Fan Zhang, Qiang Fu. Formaldehyde catalytic oxidation over hydroxyapatite modified with various organic molecules[J]. Chinese Journal of Catalysis, ;2014, 35(12): 1927-1936. doi: 10.1016/S1872-2067(14)60129-7 shu

Formaldehyde catalytic oxidation over hydroxyapatite modified with various organic molecules

Yahui Sun ^a ,
Zhenping Qu ^a,, ,
Dan Chen ^a ,
Hui Wang ^a ,
Fan Zhang ^b ,
Qiang Fu ^b

1.
a. Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian116024, Liaoning, China;

Corresponding author: Zhenping Qu,
Received Date: 13 April 2014
Available Online: 28 April 2014
Fund Project: 国家自然科学基金(21377016) (21377016) 中央高校基本科研业务费专项资金(DUT13LK27) (DUT13LK27) 长江学者和创新团队发展计划 (IRT_13R05). (IRT_13R05)

Hydroxyapatite (HAP) was modified by adding various organic molecules, such as cetyltrimethylammonium bromide, sodium dodecyl sulfate, and sodium citrate, during the precipitation of HAP. Sodium citrate-modified HAP displayed the best activity for formaldehyde oxidation, achieving complete conversion at 240 ℃. The influence of the organic modifiers on the structure of HAP was assessed by X-ray diffraction, Fourier transform infrared spectroscopy, N₂ adsorption- desorption, scanning electron microscopy, and thermogravimetry/derivative thermogravimetry. The higher specific surface area and pore volume, and smaller pores, owing to modification with sodium citrate, favored adsorption, mass transfer, and interaction process during formaldehyde oxidation. Furthermore, the higher hydroxyl group content observed in sodium citrate- modified HAP enhanced interactions between formaldehyde and HAP, thus resulting in higher catalytic activity.
- Modified hydroxyapatite,
- Sodium citrate,
- Specific surface area,
- Hydroxyl group,
- Formaldehyde catalytic oxidation
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