Citation: Cuong Duong-Viet, Housseinou Ba, Yuefeng Liu, Lai Truong-Phuoc, Jean-Mario Nhut, Cuong Pham-Huu. Nitrogen-doped carbon nanotubes on silicon carbide as a metal-free catalyst[J]. Chinese Journal of Catalysis, ;2014, 35(6): 906-913. doi: 10.1016/S1872-2067(14)60116-9 shu

Nitrogen-doped carbon nanotubes on silicon carbide as a metal-free catalyst

1.
a Institute of Chemistry and Processes for Energy, Environment and Health (ICPEES), ECPM, UMR 7515 du CNRS-University of Strasbourg, 25 rue Becquerel, 67087 Strasbourg Cedex 02, France;

Corresponding author: Yuefeng Liu, Cuong Pham-Huu,
Received Date: 31 March 2014
Available Online: 21 April 2014

A hierarchical metal-free catalyst consisting of nitrogen-doped carbon nanotubes decorated onto a silicon carbide (N-CNTs/SiC) macroscopic host structure was prepared. The influence of N-CNTs incorporation on the physical properties of the support was evaluated using different characterization techniques. The catalyst was tested as a metal-free catalyst in the selective oxidation of H₂S and steam-free dehydrogenation of ethylbenzene. The N-CNTs/SiC catalyst exhibited extremely good desulfurization performance compared to a Fe₂O₃/SiC catalyst under less conducive reaction conditions such as low temperature, high space velocity, and a low O₂-to-H₂S molar ratio. For the dehydrogenation of ethylbenzene, a higher dehydrogenation activity was obtained with the N-CNTs/SiC catalyst compared to a commercial K-Fe/Al₂O₃ catalyst. The N-CNTs/SiC catalyst also displayed good stability as a function of time on stream for both reactions, which was attributed to the strong anchoring of the nitrogen dopant in the carbon matrix. The extrudate shape of the SiC support allowed the direct macroscopic shaping of the catalyst for use in a conventional fixed-bed reactor without the problems of catalyst handling, transportation, and pressure drop across the catalyst bed that are encountered with nanoscopic carbon-based catalysts.
- Nitrogen-doped carbon nanotubes,
- Silicon carbide,
- Selective oxidation,
- H₂S,
- Dehydrogenation,
- Ethylbenzene
1. [1]
  [1] Yasuda S, Yu L, Kima J, Murakoshi K. Chem Commun, 2013, 49: 9627
2. [2]
  [2] Tuci G, Zafferoni C, D'Ambrosio P, Caporali S, Ceppatelli M, Rossin A, Tsoufis T, Innocenti M, Giambastiani G. ACS Catal, 2013, 3: 2108
3. [3]
  [3] Qu L T, Liu Y, Baek J-B, Dai L M. ACS Nano, 2010, 4: 1321
4. [4]
  [4] Nederlof C, Kapteijn F, Makkee M. Appl Catal A, 2012, 417-418: 163
5. [5]
  [5] Bégin D, Ulrich G, Amadou J, Su D S. Pham-Huu C, Ziessel R. J Mol Catal A, 2009, 302: 119
6. [6]
  [6] Chen C L, Zhang J, Zhang B S, Yu C L, Peng F, Su D S. Chem Commun, 2013, 49: 8151
7. [7]
  [7] Amadou J, Chizari K, Houllé M, Janowska I, Ersen O, Bégin D, Pham-Huu C. Catal Today,2008, 138: 62
8. [8]
  [8] Villa A, Tessonnier J P, Majoulet O, Su D S, Schlögl R. Chem Commun, 2009: 4405
9. [9]
  [9] Villa A, Tessonnier J P, Majoulet O, Su D S, R. Schlögl R. ChemSusChem,2010, 3: 241
10. [10]
  [10] Cao Y H, Yu H, Tan J, Peng F, Wang H J, Li J, Zheng W X, Wong N B. Carbon, 2013, 57: 433
11. [11]
  [11] Chizari K, Deneuve A, Ersen O, Florea I, Liu Y, Edouard D, Janowska T, Begin D, Pham-Huu C. ChemSusChem, 2012,5: 102
12. [12]
  [12] Long J L, Xie X Q, Xu J, Gu Q, Chen L M, Wang X X. ACS Catal, 2012, 2: 622
13. [13]
  [13] Su D S, Perathoner S, Centi G. Chem Rev, 2013, 113: 5782
14. [14]
  [14] Wang H B, Maiyalagan T, Wang X. ACS Catal, 2012, 2: 781
15. [15]
  [15] Yu D S, Nagelli E, Du F, Dai L M. J Phys Chem Lett, 2010, 1: 2165
16. [16]
  [16] Peng S, Cho K. Nano Lett, 2003, 3: 513
17. [17]
  [17] Su D S, Zhang J, Frank B, Thomas A, Wang X C, Paraknowitsch J, Schlögl R. ChemSusChem, 2010, 3: 169
18. [18]
  [18] Luo J, Peng F, Wang H, Yu H. Catal Commun, 2013, 39: 44
19. [19]
  [19] Gao Y J, Hu G, Zhong J, Shi Z J, Zhu Y S, Su D S, Wang J G, Bao X H, Ma D. Angew Chem Int Ed, 2013, 52: 2109
20. [20]
  [20] Liu Y F, Nguyen L D, Truong-Huu T, Liu Y, Romero T, Janowska I, Begin D, Pham-Huu C. Mater Lett, 2012, 79: 128
21. [21]
  [21] Nguyen P, Pham C. Appl Catal A, 2011, 391: 443
22. [22]
  [22] Deneuve A, Florea I, Ersen O, Nguyen P, Pham C, Begin D, Edouard D, Ledoux M J, Pham-Huu C. Appl Catal A, 2010, 385: 52
23. [23]
  [23] Florea I, Ersen O, Hirlimann C, Roiban L, Deneuve A, Houllé M, Janowska I, Nguyen P, Pham C, Pham-Huu C. Nanoscale, 2010, 2: 2668
24. [24]
  [24] Liu Y F, Ersen O, Meny C, Luck F, Pham-Huu C. ChemSusChem, 2014, DOI: 10.1002/cssc.201300921
25. [25]
  [25] Chizari K, Janowska I, Houllé M, Florea I, Ersen O, Romero T, Bernhardt P, Ledoux M J, Pham-Huu C. Appl Catal A, 2010, 380: 72
26. [26]
  [26] Louis B, Gulino G, Vieira R, Amadou J, Dintzer T, Galvagno S, Centi G, Ledoux MJ, Pham-Huu C. Catal Today, 2005, 102-103: 23
27. [27]
  [27] Florea I, Ersen O, Arenal R, Ihiawakrim D, Messaoudi C, Chizari K, Janowska I, Pham-Huu C. J Am Chem Soc, 2012, 134: 9672
28. [28]
  [28] Terrones M, Benito A M, Manteca-DiegoC, Hsu W K, Osman O I, Hare J P, Reid D G, Terrones H, Cheetham A K, Prassides K, Kroto H W, Walton D R M. Chem Phys Lett, 1996, 257: 576
29. [29]
  [29] Zhong D Y, Lin S, Zhang G Y, Wang E G. J Appl Phys, 2001, 89: 5939
30. [30]
  [30] Chizari K, Vena A, Laurentius L, Sundararaj U. Carbon, 2014, 68: 369
31. [31]
  [31] Biniak S, Szymanski G, Siedlewski J, Wiatkoski A. Carbon, 1997,35: 1799
32. [32]
  [32] Choi H C, Park J, Kim B. J Phys Chem B, 2005, 109: 4333
33. [33]
  [33] Choi H C, SBae S Y, Park J, Seo K, Kim C, Kim B, Song H J, Shin H J. Appl Phys Lett, 2004, 85: 5742
34. [34]
  [34] Strelko V V, Kartel N T, Dukhno I N, Kuts V S, Clarkson R B, Odintsov B M. Surf Sci, 2004, 548: 281
35. [35]
  [35] Gulino G, Vieira R, Amadou J, Nguyen P, Ledoux M J, Galvagno S, Centi G, Pham-Huu C. Appl Catal A, 2005, 279: 89
36. [36]
  [36] Liu Y F, Dintzer T, Ersen O, Pham-Huu C. J Energy Chem, 2013, 22: 279
37. [37]
  [37] Keller N, Pham-Huu C, Crouzet C, Ledoux M J, Savin-Poncet S, Nougayrede J B, Bousquet J. Catal Today, 1999, 53: 535
38. [38]
  [38] Nguyen P, Edouard D, Nhut J M, Ledoux M J, Pham C, Pham-Huu C. Appl Catal B, 2007, 76: 300
39. [39]
  [39] Zhao Q, Feillinger T P, Antoneitti M, Yuan J. J Mater Chem A, 2013, 1: 5113
40. [40]
  [40] Gong K P, Du F, Xia Z H, Durstock M, Dai L M. Science, 2009, 323: 760
41. [41]
  [41] Keller N, Pham-Huu C, Ledoux M J. Appl Catal A, 2001, 217: 205
42. [42]
  [42] Zhang J, Su D S, Blume R, Schlogl R, Wang R, Yang X G, Gajovic A. Angew Chem Int Ed, 2010, 49: 8640
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