Citation: Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattnaik, Anita Routaray, Nibedita Nath, Prasanta Rath, Tungabidya Maharana. Novel polystyrene-anchored zinc complex：Efficient catalyst for phenol oxidation[J]. Chinese Journal of Catalysis, ;2014, 35(10): 1701-1708. doi: 10.1016/S1872-2067(14)60113-3 shu

Novel polystyrene-anchored zinc complex：Efficient catalyst for phenol oxidation

1.
a Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India;

Corresponding author: Alekha Kumar Sutar,
Received Date: 6 March 2014
Available Online: 15 April 2014

The novel recyclable free -ONNO-tetradentate Schiff base ligand N,N'-bis(2-hydroxy-3-methoxybenzaldehyde)4-methylbenzene-1,2-diamine (3-MOBdMBn) was synthesized. Complexation of this ligand with zinc (3-MOBdMBn-Zn) was performed, and the catalytic activity of the complex was evaluated. The polymer-supported analog of this complex (P-3-MOBdMBn-Zn) was synthesized, and its catalytic activity was studied. These free and polymer-anchored zinc complexes were prepared by the reactions of metal solutions with one molar equivalent of unsupported 3-MOBdMBn or P-3-MOBdMBn in methanol under nitrogen. The catalytic activity of 3-MOBdMBn-Zn and P-3-MOBdMBn-Zn was evaluated in phenol oxidation. The activity of P-3-MOBdMBn-Zn was significantly affected by the polymer support, and the rate of phenol conversion was around 50% for polystyrene-supported 3-MOBdMBn. The experimental results indicated that the reaction rate was affected by the polymer support, and the rate of phenol conversion was 1.64 μmol/(L·s) in the presence of polystyrene-supported 3-MOBdMBn.
- Polystyrene,
- Schiff base,
- Polymer support,
- Catalysis,
- Zinc,
- Phenol oxidation
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沈阳化工大学材料科学与工程学院沈阳 110142