Citation: Olga Yu. Podyacheva, Andrei I. Stadnichenko, Svetlana A. Yashnik, Olga A. Stonkus, Elena M. Slavinskaya, Andrei I. Boronin, Andrei V. Puzynin, Zinfer R. Ismagilov. Catalytic and capacity properties of nanocomposites based on cobalt oxide and nitrogen-doped carbon nanofibers[J]. Chinese Journal of Catalysis, ;2014, 35(6): 960-969. doi: 10.1016/S1872-2067(14)60099-1 shu

Catalytic and capacity properties of nanocomposites based on cobalt oxide and nitrogen-doped carbon nanofibers

1.
a Boreskov Institute of Catalysis, Pr. Akademika Lavrentieva 5, Novosibirsk 630090, Russia;

Corresponding author: Olga Yu. Podyacheva,
Received Date: 27 March 2014
Available Online: 9 April 2014
Fund Project: This work was supported by RFBR Grant 12-03-01091-a, Presidium RAS (Project 24.51) (Project 24.51) Presidium SB RAS (Project 36, Project 75). (Project 36, Project 75)

The nanocomposites based on cobalt oxide and nitrogen-doped carbon nanofibers (N-CNFs) with cobalt oxide contents of 10-90 wt% were examined as catalysts in the CO oxidation and supercapacity electrodes. Depending on Co₃O₄ content, such nanocomposites have different morphologies of cobalt oxide nanoparticles, distributions over the bulk, and ratios of Co³⁺/Co²⁺ cations. The 90%Co₃O₄-N-CNFs nanocomposite showed the best activity because of the increased concentration of defects in N-CNFs. The capacitance of electrodes containing 10%Co₃O₄-N-CNFs was 95 F/g, which is 1.7 times higher than electrodes made from N-CNFs.
- Cobalt oxide,
- Nitrogen-doped carbon nanofibers,
- Nanocomposite,
- CO oxidation,
- Capacity
1. [1]
  [1] Casas-Cabanas M, Binotto G, Larcher D, Lecup A, Giordani V, Tarascon J M. Chem Mater, 2009, 21: 1939
2. [2]
  [2] Li W Y, Xu L N, Chen J. Adv Funct Mater, 2005, 15: 851
3. [3]
  [3] Farhadi S, Safabakhsh J, Zaringhadam P. J Nanostructure Chem, 2013, 3: 69
4. [4]
  [4] Wang X, Tian W, Zhai T Y, Zhi C Y, Bando Y, Golberg D. J Mater Chem, 2012, 22: 23310
5. [5]
  [5] Royer S, Duprez D. ChemCatChem, 2011, 3: 24
6. [6]
  [6] Jansson J. J Catal, 2000, 194: 55
7. [7]
  [7] Yu Y B, Takei T, Ohashi H, He H, Zhang X L, Haruta M. J Catal,2009,267: 121
8. [8]
  [8] Xie X W, Li Y, Liu Z Q, Haruta M, Shen W J. Nature, 2009, 458: 746
9. [9]
  [9] Ren Y, Ma Z, Qian L P, Dai S, He H Y, Bruce P G. Catal Lett, 2009, 131: 146
10. [10]
  [10] Jia C J, Schwickardi M, Weidenthaler C, Schmidt W, Korhonen S, Weckhuysen B M, Schüth F. J Am Chem Soc, 2011, 133: 11279
11. [11]
  [11] Li D B, Liu X H, Zhang Q H, Wang Y, Wan H L. Catal Lett, 2009, 127: 377
12. [12]
  [12] Tang C W, Wang C B, Chien S H. Catal Lett, 2009, 131: 76
13. [13]
  [13] Su D S, Perathoner S, Centi G. Chem Rev, 2013, 113: 5782
14. [14]
  [14] Zhu J, Holmen A, Chen D. ChemCatChem, 2013, 5: 378
15. [15]
  [15] Su D S, Perathoner S, Centi G. Catal Today, 2012, 186: 1
16. [16]
  [16] Bitter J H. J Mater Chem, 2010, 20: 7312
17. [17]
  [17] Antolini E. Appl Catal B, 2009, 88: 1
18. [18]
  [18] Amadou J, Chizari K, Houlle M, Janowska I, Ersen O, Begin D, Pham-Huu C. Catal Today, 2008, 138: 62
19. [19]
  [19] Garcia-Garcia F R, Alvarez-Rodriguez J, Rodriguez-Ramos I, Guerrero-Ruiz A. Carbon, 2010, 48: 267
20. [20]
  [20] Bezemer G L, van Laak A, van Dillen A J, de Jong K P. Stud Surf Sci Catal, 2004, 147: 259
21. [21]
  [21] Bezemer G L, Radstake P B, Koot V, van Dillen A J, Geus J W, de Jong K P. J Catal, 2006, 237: 291
22. [22]
  [22] Lim H D, Gwon H, Kim H, Kim S W, Yoon T, Choi J W, Oh S M, Kang K. Electrochim Acta, 2013, 90: 63
23. [23]
  [23] Lang J W, Yan X B, Xue Q J. J Power Sources, 2011, 196: 7841
24. [24]
  [24] Ewels C P, Glerup M. J Nanosci Nanotechnol, 2005, 5: 1345
25. [25]
  [25] Terrones M, Jorio A, Endo M, Rao A M, Kim Y A, Hayashi T, Terrones H, Charlier J C, Dresselhaus G, Dresselhaus M S. Mater Today, 2004, 7(10): 30
26. [26]
  [26] van Dommele S, de Jong K P, Bitter J H. Chem Commun, 2006: 4859
27. [27]
  [27] Maldonado S, Morin S, Stevenson K J. Carbon, 2006, 44: 1429
28. [28]
  [28] Ismagilov Z R, Shalagina A E, Podyacheva O Yu, Ischenko A V, Kibis L S, Boronin A I, Chesalov Y A, Kochubey D I, Romanenko A I, Anikeeva O B, Buryakov T I, Tkachev E N. Carbon, 2009, 47: 1922
29. [29]
  [29] Podyacheva O Yu, Ismagilov Z R, Boronin A I, Kibis L S, Slavinskaya E M, Noskov A S, Shikina N V, Ushakov V A, Ischenko A V. Catal Today, 2012, 186: 42
30. [30]
  [30] Shalagina A E, Ismagilov Z R, Podyacheva O Yu, Kvon R I, Ushakov V A. Carbon, 2007, 45: 1808
31. [31]
  [31] Mateyshina Y, Ulihin A, Samarov A, Barnakov C, Uvarov N. Solid State Ionics, 2013, 251: 59
32. [32]
  [32] Hutchings K N, Wilson M, Larsen P A, Cutler R A. Solid State Ionics, 2006, 177: 45
33. [33]
  [33] Radwan N R E, El-Shobaky H G. Thermochim Acta, 2000, 360: 147
34. [34]
  [34] Dervishi E, Li Z R, Biris A R, Lupu D, Trigwell S, Biris A S. Chem Mater, 2007, 19: 179
35. [35]
  [35] Dervishi E, Li Z R, Watanabe F, Xu Y, Saini V, Biris A R, Biris A S. J Mater Chem, 2009, 19: 3004
36. [36]
  [36] Zhang J S, Grzelczak M, Hou Y D, Maeda K, Domen K, Fu X Z, Antoniettu M, Wang X C. Chem Sci, 2012, 3: 443
37. [37]
  [37] Chuang T J, Brundle C R, Rice D W. Surf Sci, 1976, 59: 413
38. [38]
  [38] Natile M M, Glisenti A. Chem Mater, 2002, 14: 3090
39. [39]
  [39] Zhu H W, Razzaq R, Jiang L, Li C S. Catal Commun, 2012, 23: 43
40. [40]
  [40] Wang S J, Zhang B P, Zhao C H, Li S J, Zhang M X, Yan L P. Appl Surf Sci, 2011, 257: 3358
41. [41]
  [41] Jiang S J, Song S Q. Appl Catal B, 2013, 140-141: 1
42. [42]
  [42] Jimenez V M, Fernandez A, Espinos J P, Gonzalez-Elipe A R. J Electron Spectr Rel Phen, 1995, 71: 61
43. [43]
  [43] Sexton B A, Hughes A E, Turney T W. J Catal, 1986, 97: 390
44. [44]
  [44] Tang C W, Wang C B, Chien S H. Thermochim Acta, 2008, 473: 68
45. [45]
  [45] Jacobs G, Ji Y Y, Davis B H, Cronauer D, Kropf A J, Marshall C L. Appl Catal A, 2007, 333: 177
46. [46]
  [46] Tomic-Tucakovic B, Majstorovic D, Jelic D, Mentus S. Thermochim Acta, 2012, 541: 15
47. [47]
  [47] Hwang S G, Ryu S H, Yun S R, Ko J M, Kim K M, Ryu K S. Mater Chem Phys, 2011, 130: 507
48. [48]
  [48] Liu J S, Hu Y, Chuang T L, Huang C L. Thin Solid Films, 2013, 544: 186
49. [49]
  [49] Jia C J, Liu Y, Bongard H, Schüth F. J Am Chem Soc, 2010, 132: 1520
50. [50]
  [50] Cunningham D A H, Vogel W, Haruta M. Catal Lett, 1999, 63: 43
51. [51]
  [51] Liu H L, Wang Y, Gou X L, Qi T, Yang J, Ding Y L. Mater Sci Eng B, 2013, 178: 293
1. [1]
  Yanjie Li , Chaoqun Qu , Siqi Meng , Jiaqi Hu , Ze Gao , Hongji Xu , Rui Gao , Ming Feng . Revealing electronic state evolution of Co(Ⅱ)/Co(Ⅲ) in CoO (111) plane during OER process through magnetic measurement. Chinese Chemical Letters, 2025, 36(3): 109872-. doi: 10.1016/j.cclet.2024.109872
2. [2]
  Jumei Zhang , Ziheng Zhang , Gang Li , Hongjin Qiao , Hua Xie , Ling Jiang . Ligand-mediated reactivity in CO oxidation of yttrium-nickel monoxide carbonyl complexes. Chinese Chemical Letters, 2025, 36(2): 110278-. doi: 10.1016/j.cclet.2024.110278
3. [3]
  Fereshte Hassanzadeh-Afruzi , Mina Azizi , Iman Zare , Ehsan Nazarzadeh Zare , Anwarul Hasan , Siavash Iravani , Pooyan Makvandi , Yi Xu . Advanced metal-organic frameworks-polymer platforms for accelerated dermal wound healing. Chinese Chemical Letters, 2024, 35(11): 109564-. doi: 10.1016/j.cclet.2024.109564
4. [4]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
5. [5]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
6. [6]
  Jiahao Xie , Jin Liu , Bin Liu , Xin Meng , Zhuang Cai , Xiaoqin Xu , Cheng Wang , Shijie You , Jinlong Zou . Yolk shell-structured pyrite-type cobalt sulfide grafted by nitrogen-doped carbon-needles with enhanced electrical conductivity for oxygen electrocatalysis. Chinese Chemical Letters, 2024, 35(7): 109236-. doi: 10.1016/j.cclet.2023.109236
7. [7]
  Xiujuan Wang , Yijie Wang , Luyun Cui , Wenqiang Gao , Xiao Li , Hong Liu , Weijia Zhou , Jingang Wang . Coordination-based synthesis of Fe single-atom anchored nitrogen-doped carbon nanofibrous membrane for CO₂ electroreduction with nearly 100% CO selectivity. Chinese Chemical Letters, 2024, 35(12): 110031-. doi: 10.1016/j.cclet.2024.110031
8. [8]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
9. [9]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
10. [10]
  Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang . Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix. Chinese Chemical Letters, 2025, 36(2): 110444-. doi: 10.1016/j.cclet.2024.110444
11. [11]
  Yan Wang , Jiaqi Zhang , Xiaofeng Wu , Sibo Wang , Masakazu Anpo , Yuanxing Fang . Elucidating oxygen evolution and reduction mechanisms in nitrogen-doped carbon-based photocatalysts. Chinese Chemical Letters, 2025, 36(2): 110439-. doi: 10.1016/j.cclet.2024.110439
12. [12]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
13. [13]
  Wenjing Dai , Lan Luo , Zhen Yin . Interface reconstruction of hybrid oxide electrocatalysts for seawater oxidation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100442-100442. doi: 10.1016/j.cjsc.2024.100442
14. [14]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
15. [15]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
16. [16]
  Shimei Wu , Yining Li , Lantao Chen , Yufei Zhang , Lingxing Zeng , Haosen Fan . Hexapod cobalt phosphosulfide nanorods encapsulating into multiple hetero-atom doped carbon frameworks for advanced sodium/potassium ion battery anodes. Chinese Chemical Letters, 2025, 36(4): 109796-. doi: 10.1016/j.cclet.2024.109796
17. [17]
  Husitu Lin , Shuangkun Zhang , Dianfa Zhao , Yongkang Wang , Wei Liu , Fan Yang , Jianjun Liu , Dongpeng Yan , Zhanpeng Wu . Flexible polyphosphazene nanocomposite films: Enhancing stability and luminescence of CsPbBr₃ perovskite nanocrystals. Chinese Chemical Letters, 2025, 36(4): 109795-. doi: 10.1016/j.cclet.2024.109795
18. [18]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
19. [19]
  Hao Zhang , Haonan Qu , Ehsan Bahojb Noruzi , Haibing Li , Feng Liang . A nanocomposite film with layer-by-layer self-assembled gold nanospheres driven by cucurbit[7]uril for the selective transport of L-tryptophan and lysozyme. Chinese Chemical Letters, 2025, 36(1): 109731-. doi: 10.1016/j.cclet.2024.109731
20. [20]
  Tao Wei , Jiahao Lu , Pan Zhang , Qi Zhang , Guang Yang , Ruizhi Yang , Daifen Chen , Qian Wang , Yongfu Tang . An intermittent lithium deposition model based on bimetallic MOFs derivatives for dendrite-free lithium anode with ultrahigh areal capacity. Chinese Chemical Letters, 2024, 35(8): 109122-. doi: 10.1016/j.cclet.2023.109122

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(463)
HTML views(56)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142