Citation: Min Wang, Feng Wang. What and where are the active sites of oxide-supported nanostructured metal catalysts?[J]. Chinese Journal of Catalysis, ;2014, 35(4): 453-456. doi: 10.1016/S1872-2067(14)60073-5 shu

What and where are the active sites of oxide-supported nanostructured metal catalysts?

Min Wang ,
Feng Wang ^,

1.
Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Corresponding author: Feng Wang,
Received Date: 30 December 2013

Fund Project: 国家自然科学基金(21303189, 21273231, 21233008) (21303189, 21273231, 21233008)

The oxide-supported metal catalysts constitute the most investigated catalyst in both academia and industry. This perspective highlights recent research progresses on the topic, which may shed light on the nature and location of the active sites.
- Nanoparticle,
- Metal support interaction,
- Perimeter atom,
- Interface,
1. [1]
  [1] Haruta M. Faraday Discuss, 2011, 152: 11
2. [2]
  [2] Kuwauchi Y, Yoshida H, Akita T, Haruta M, Takeda S. Angew Chem Int Ed, 2012, 51: 7729
3. [3]
  [3] Yang M, Allard L F, Flytzani-Stephanopoulos M. J Am Chem Soc, 2013, 135: 3768
4. [4]
  [4] Ta N, Liu J Y, Chenna S, Crozier P A, Li Y, Chen A L, Shen W J. J Am Chem Soc, 2012, 134: 20585
5. [5]
  [5] Chen C, Nan C, Wang D, Su Q, Duan H, Liu X, Zhang L, Chu D, Song W, Peng Q, Li Y. Angew Chem Int Ed, 2011, 50: 3725
6. [6]
  [6] Wang M, Wang F, Ma J P, Chen C, Shi S, Xu J. Chem Commun, 2013, 49: 6623
7. [7]
  [7] Hayek K, Kramer R, Paal Z. Appl Catal A, 1997, 162: 1
8. [8]
  [8] Schubert M M, Hackenberg S, van Veen A C, Muhler M, Plzak V, Behm R J. J Catal, 2001, 197: 113
9. [9]
  [9] Liu X Y, Wang A Q, Zhang T, Mou C Y. Nano Today, 2013, 8: 403
10. [10]
  [10] Jenness G R, Schmidt J R. ACS Catal, 2013, 3: 2881
11. [11]
  [11] Yoon B, Hakkinen H, Landman U, Worz A S, Antonietti J M, Abbet S, Judai K, Heiz U. Science, 2005, 307: 403
12. [12]
  [12] Wang F, Ueda W, Xu J. Angew Chem Int Ed, 2012, 51: 3883
13. [13]
  [13] Wang Y H, Wang F, Song Q, Xin Q, Xu S T, Xu J. J Am Chem Soc, 2013, 135: 1506
14. [14]
  [14] Ta N, Liu J Y, Shen W J. Chin J Catal (塔娜, 刘景月, 申文杰. 催化学报), 2013, 34: 838
15. [15]
  [15] Zhang H L, Ren L H, Lu A H, Li W C. Chin J Catal (张慧丽, 任丽会, 陆安慧, 李文翠. 催化学报), 2012, 33: 1125
16. [16]
  [16] Si R, Flytzani-Stephanopoulos M. Angew Chem Int Ed, 2008, 47: 2884
17. [17]
  [17] Abad A, Concepcion P, Corma A, Garcia H. Angew Chem Int Ed, 2005, 44: 4066
18. [18]
  [18] Fu Q, Saltsburg H, Flytzani-Stephanopoulos M. Science, 2003, 301: 935
19. [19]
  [19] Wang M, Wang F, Ma J P, Li M R, Zhang Z, Wang Y H, Zhang X C, Xu J. Chem Commun, 2014, 50: 292
20. [20]
  [20] Cargnello M, Doan-Nguyen V V T, Gordon T R, Diaz R E, Stach E A, Gorte R J, Fornasiero P, Murray C B. Science, 2013, 341: 771
21. [21]
  [21] Fu Q, Li W X, Yao Y X, Liu H Y, Su H Y, Ma D, Gu X K, Chen L M, Wang Z, Zhang H, Wang B, Bao X H. Science, 2010, 328: 1141
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沈阳化工大学材料科学与工程学院沈阳 110142