Citation: Huimei Gan, Xiuge Zhao, Baoning Song, Li Guo, Ran Zhang, Chen Chen, Jizhong Chen, Wenwen Zhu, Zhenshan Hou. Gas phase dehydration of glycerol to acrolein catalyzed by zirconium phosphate[J]. Chinese Journal of Catalysis, ;2014, 35(7): 1148-1156. doi: 10.1016/S1872-2067(14)60057-7 shu

Gas phase dehydration of glycerol to acrolein catalyzed by zirconium phosphate

1.
Key Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: Zhenshan Hou,
Received Date: 20 December 2013
Available Online: 20 February 2014
Fund Project:

Zirconium phosphates were prepared by precipitation, hydrothermal synthesis, and impregnation methods and were characterized by X-ray diffraction, thermogravimetric analysis, nitrogen adsorption, Fourier transform infrared spectroscopy, and Hammett indicators. The different preparation methods have crucial effects on the texture and surface acidity of the zirconium phosphates. The zirconium phosphates were employed as catalysts for the gas phase dehydration of glycerol under mild reaction conditions. The zirconium phosphates from the precipitation method afforded the highest activity with the complete conversion of glycerol, 81% selectivity to acrolein, and no obvious deactivation over 24 h. Surface acidic sites played an important role in the activity, selectivity to acrolein, and life of catalysts.
- Glycerol,
- Dehydration,
- Acrolein,
- Zirconium phosphate,
- Acidity
1. [1]
  [1] Ng J H, Ng H K, Gan S. Clean Technol Environol Policy, 2010, 12: 459
2. [2]
  [2] Atabani A E, Silitonga A S, Ong H C, Mahlia T M I, Masjuki H H, Badruddin I A, Fayaz H. Renew Sustain Energy Rev, 2013, 18: 211
3. [3]
  [3] Beatrice C, Blasio G D, Lazzaro M, Cannilla C, Bonura G, Frusteri F, Asdrubali F, Baldinelli G, Presciutti A, Fantozzi F, Bidini G, Bartocci P. Appl Energy, 2013, 102: 63
4. [4]
  [4] Dubois J L. US Patent 20120283479. 2012
5. [5]
  [5] Katryniok B, Paul S, Dumeignil F. ACS Catal, 2013, 3: 1819
6. [6]
  [6] Bühler W, Dinjus E, Ederer H J, Kruse A, Mas C. J Supercrit Fluids, 2002, 22: 37
7. [7]
  [7] Watanabe M, Iida T, Aizawa Y, Aida T M, Inomata H. Bioresour Technol, 2007, 98: 1285
8. [8]
  [8] Lehr V, Sarlea M, Ott L, Vogel H. Catal Today, 2007, 121: 121
9. [9]
  [9] Tsukuda E, Sato S, Takahashi R, Sodesawa T. Catal Commun, 2007, 8: 1349
10. [10]
  [10] Ning L L, Ding Y J, Chen W M, Gong L F, Lin R H, Lü Y, Xin Q. Chin J Catal (宁丽丽, 丁云杰, 陈维苗, 龚磊峰, 林荣和, 吕元, 辛勤. 催化学报), 2008, 29: 212
11. [11]
  [11] Chai S H, Wang H P, Liang Y, Xu B Q. Appl Catal A, 2009, 353: 213
12. [12]
  [12] Shen L Q, Feng Y H, Yin H B, Wang A L, Yu L B, Jiang T S, Shen Y T, Wu Z A. J Ind Eng Chem, 2011, 17: 484
13. [13]
  [13] Liu R, Wang T F, Liu C, Jin Y. Chin J Catal (刘蓉, 王铁峰, 刘畅, 金涌. 催化学报), 2013, 34: 2174
14. [14]
  [14] Ulgen A, Hoelderich W. Catal Lett, 2009, 131: 122
15. [15]
  [15] Ulgen A, Hoelderich W. Appl Catal A, 2011, 400: 34
16. [16]
  [16] Lauriol-Garbay P, Millet J M M, Loridant S, Bellière-Baca V, Rey P. J Catal, 2011, 280: 68
17. [17]
  [17] Corma A, Huber G W, Sauvanaud L, O'Connor P. J Catal, 2008, 257: 163
18. [18]
  [18] Kim Y T, Jung K D, Park E D. Appl Catal A, 2011, 393: 275
19. [19]
  [19] Lourenco J P, Macedo M I, Fernandes A. Catal Commun, 2012, 19: 105
20. [20]
  [20] Wang F, Dubois J L, Ueda W. J Catal, 2009, 268: 260
21. [21]
  [21] Wang F, Dubois J L, Ueda W. Appl Catal A, 2010, 376: 25
22. [22]
  [22] Deleplanque J, Dubois J L, Devaux J F, Ueda W. Catal Today, 2010, 157: 351
23. [23]
  [23] Suprun W, Lutecki M, Gläser R, Papp H. J Mol Catal A, 2011, 342-343: 91
24. [24]
  [24] Pethan Rajan N, Rao G S, Pavankumar V, Chary K V R. Catal Sci Technol, 2014, 4: 81
25. [25]
  [25] Haider M H, Dummer N F, Zhang D Z, Miedziak P, Davies T E, Taylor S H, Willock D J, Knight D W, Chadwick D, Hutchings G J. J Catal, 2012, 286: 206
26. [26]
  [26] Chai S H, Wang H P, Liang Y, Xu B Q. J Catal, 2007, 250: 342
27. [27]
  [27] Alhanash A, Kozhevnikova E F, Kozhevnikov I V. Appl Catal A, 2010, 378: 11
28. [28]
  [28] Sinhamahapatra A, Sutradhar N, Roy B, Pal P, Bajaj H C, Panda A B. Appl Catal B, 2011, 103: 378
29. [29]
  [29] Das S K, Bhunia M K, Sinha A K, Bhaumik A. ACS Catal, 2011, 1: 493
30. [30]
  [30] Khare S, Chokhare R. J Mol Catal A, 2011, 344: 83
31. [31]
  [31] Weingarten R, Kim Y T, Tompsett G A, Fernández A, Han K S, Hagaman E W, Conner W C Jr, Dumesic J A, Huber G W. J Catal, 2013, 304: 123
32. [32]
  [32] Ordomsky V V, Sushkevich V L, Schouten J C, van der Schaaf J, Nijhuis T A. J Catal, 2013, 300: 37
33. [33]
  [33] Cui H, Li Q, Gao S, Shang J K. J Ind Eng Chem, 2012, 18: 1418
34. [34]
  [34] Burnell V A, Readman J E, Tang C C, Parker J E, Thompson S P, Hriljac J A. J Solid State Chem, 2010, 183: 2196
35. [35]
  [35] Sinhamahapatra A, Sutradhar N, Roy B, Tarafdar A, Bajaj H C, Panda A B. Appl Catal A, 2010, 385: 22
36. [36]
  [36] Weingarten R, Tompsett G A, Conner W C Jr, Huber G W. J Catal, 2011, 279: 174
37. [37]
  [37] Ramesh K, Hui L M, Han Y F, Borgna A. Catal Commun, 2009, 10: 567
38. [38]
  [38] Miao Z C, Xu L L, Song H L, Zhao H H, Chou L J. Catal Sci Technol, 2013, 3: 1942
39. [39]
  [39] Mao H H, Lu X H, Li M S, Yang J H, Li B S. Appl Surf Sci, 2013, 276: 787
40. [40]
  [40] Chai S H, Wang H P, Liang Y, Xu B Q. Green Chem, 2007, 9: 1130
41. [41]
  [41] Ikeda Y, Asadullah M, Fujimoto K, Tomishige K. J Phys Chem B, 2001, 105: 10653
42. [42]
  [42] Xue N H, Chen X K, Nie L, Guo X F, Ding W P, Chen Y, Gu M, Xie Z K. J Catal, 2007, 248: 20
43. [43]
  [43] Tao L Z, Yan B, Liang Y, Xu B Q. Green Chem, 2013, 15: 696
44. [44]
  [44] Chai S H, Wang H P, Liang Y, Xu B Q. Green Chem, 2008, 10: 1087
45. [45]
  [45] Tao L Z, Chai S H, Zuo Y, Zheng W T, Liang Y, Xu B Q. Catal Today, 2010, 158: 310
46. [46]
  [46] Stosic D, Bennici S, Couturier J L, Dubois J L, Auroux A. Catal Commun, 2012, 17: 23
47. [47]
  [47] Okuhara T. Chem Rev, 2002, 102: 3641
48. [48]
  [48] Kamiya Y, Sakata S, Yoshinaga Y, Ohnishi R, Okuharaa T. Catal Lett, 2004, 94: 45
49. [49]
  [49] Weingarten R, Kim Y T, Tompsett G A, Fernández A, Han K S, Hagaman E W, Conner W C Jr, Dumesic J A, Huber G W. J Catal, 2013, 304: 123
50. [50]
  [50] Ulgen A, Hoelderich W F. Appl Catal A, 2011, 400: 34
51. [51]
  [51] Garcia-Sancho C, Moreno-Tost R, Merida-Robles J, Santamaria-González J, Jimenez-López A, Maireless-Torres P. Appl Catal A, 2012, 433-434: 179
1. [1]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
2. [2]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
3. [3]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
4. [4]
  Bin HE , Hao ZHANG , Lin XU , Yanghe LIU , Feifan LANG , Jiandong PANG . Recent progress in multicomponent zirconium?based metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2041-2062. doi: 10.11862/CJIC.20240161
5. [5]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
6. [6]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
7. [7]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
8. [8]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
9. [9]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
10. [10]
  Jie Li , Huida Qian , Deyang Pan , Wenjing Wang , Daliang Zhu , Zhongxue Fang . Efficient Synthesis of Anethaldehyde Induced by Visible Light. University Chemistry, 2024, 39(4): 343-350. doi: 10.3866/PKU.DXHX202310076
11. [11]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
12. [12]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
13. [13]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
14. [14]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
15. [15]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
16. [16]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
17. [17]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(435)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142