Citation: Qunying Liang, Hong Su, Jing Yan, Chunkit Leung, Shuiliang Cao, Dingsheng Yuan. N-doped mesoporous carbon as a bifunctional material for oxygen reduction reaction and supercapacitors[J]. Chinese Journal of Catalysis, ;2014, 35(7): 1078-1083. doi: 10.1016/S1872-2067(14)60044-9 shu

N-doped mesoporous carbon as a bifunctional material for oxygen reduction reaction and supercapacitors

1.
a. Department of Chemistry, Jinan University, Guangzhou 510632, Guangdong, China;

Corresponding author: Dingsheng Yuan,
Received Date: 30 December 2013
Available Online: 22 January 2014
Fund Project:

A N-doped mesoporous carbon (NMC-1) has been synthesized at relatively low temperature using chitosan as a nitrogen and carbon source, tetraethoxysilane as a soft template, and nickel nitrate as a catalyst. NMC-1 has a porous structure and heteroatoms such as N and O atoms, indicating that NMC-1 can contribute to electrocatalysis, electric double-layer capacitance, and pseudocapacitance. Hence, NMC-1 was used as a bifunctional material which shows effective activity as an electrocatalyst for oxygen reduction reaction in alkaline solution, and a high specific capacitance as an ultracapacitor (252 F/g at 0.2 A/g). The results demonstrate that the presented NMC-1 has potential applications as a renewable and environmentally friendly material in fuel cells and supercapacitors.
- N-doped mesoporous,
- carbon chitosan,
- electrocatalyst,
- oxygen reduction reaction,
- supercapacitor
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沈阳化工大学材料科学与工程学院沈阳 110142